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Perkin Transactions 1 1972-2002 logo

Year 1977
Main Index

Issue 0


Errata

pg X001; DOI:
10.1039/P1977000X001
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Notices to authors

pg X002; DOI:
10.1039/P1977000X002
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Index of authors, 1977

pg 2613; DOI:
10.1039/P19770002613
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Index of subjects, 1977

pg 2637; DOI:
10.1039/P19770002637
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Issue 1


Contents pages

pg P001; DOI:
10.1039/P197700FP001
PDF
Microbial transformations of glaucine
Patrick J. Davis Daniel Wiese and John P. Rosazza
pg 1; DOI:
10.1039/P19770000001
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Chemical investigation of Ceylonese plants. Part 20. Extractives of Mesua myrtifolia. Isolation and structure of a new triterpene hydroxy-acid, myrtifolic acid
Sarath P. Gunasekera and M. Uvais S. Sultanbawa
pg 6; DOI:
10.1039/P19770000006
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Chemical investigation of ceylonese plants. Part 21. Extractives of Pentadesma butyracea Sabine (Guttiferae)
Sarath P. Gunasekera Kanapathipillai Sivapalan M. Uvais S. Sultanbawa and W. David Ollis
pg 11; DOI:
10.1039/P19770000011
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Reactions of electron donor–acceptor systems: cycloaddition reactions of aryl-substituted olefins with tetracyanoethylene
Yasuhiko Shirota Jun-ichiro Nagata Yoshio Nakano Takashi Nogami and Hiroshi Mikawa
pg 14; DOI:
10.1039/P19770000014
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The preparation from cyclopentadiene trimer of alcohols and ketones containing the perhydro-4,9:5,8-dimethanobenz[f]indene ring system
Athelstan L. J. Beckwith and Martin L. Gilpin
pg 19; DOI:
10.1039/P19770000019
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Studies on the syntheses of heterocyclic compounds. Part 676. Synthesis of 1-substituted 7-methoxymitosenes
Tetsuji Kametani Kimio Takahashi Yoshio Kigawa Masataka Ihara and Keiichiro Fukumoto
pg 28; DOI:
10.1039/P19770000028
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Bridged ring systems. Part 19. Condensation–cyclisation reaction of acrylaldehyde with diethyl 2,5-dioxocyclohexane-1,4-dicarboxylate
Geo. L. Buchanan William B. Kennedy and Alex. M. Lawson
pg 32; DOI:
10.1039/P19770000032
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Studies in terpenoids. Part 40. Synthesis of ()-sydowic acid
Putti R. Vijayasarathy Ramachandra B. Mane and G. S. Krishna Rao
pg 34; DOI:
10.1039/P19770000034
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Dicarbonylrhodium(I) complexes of polypyrrole macrocycles. Part 1. Preparation and oxidative addition reactions with alkyl halides and carboxylic acid anhydrides
Ajita M. Abeysekera Ronald Grigg Jadwiga Trocha-Grimshaw and Venkatappa Viswanatha
pg 36; DOI:
10.1039/P19770000036
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Syntheses and 1,3-dipolar cycloaddition reactions of benz[de]isoquinolinium-1-ides
Masazumi Ikeda Yasuyoshi Miki Sumiko Kaita Yoshinori Nishikawa and Yasumitsu Tamura
pg 44; DOI:
10.1039/P19770000044
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Synthesis of heterocyclic compounds. Part 34. Reactions of chlorosulphonyl isocyanate with carbon–nitrogen double bonds
Hans Suschitzky Ralph E. Walrond and Roy Hull
pg 47; DOI:
10.1039/P19770000047
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Metabolites from microbially infected potato. Part 1. Structure of phytuberin
David T. Coxon Keith R. Price Barbara Howard and R. Frank Curtis
pg 53; DOI:
10.1039/P19770000053
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Synthesis of 1,6,7-triphenyltricyclo[4.1.0.02,7]heptan-3-one and rearrangement of 3-(1,2,3-triphenylcycloprop-2-enyl)propanoic acid
Audrey Monahan and Dennis Lewis
pg 60; DOI:
10.1039/P19770000060
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Naphtho[1,2-b]thiophen. Part 2. Substitution reactions of derivatives with one or more substituents in the thiophen ring and of the 4,5-di-hydro-derivative
Kenneth Clarke Derek N. Gregory and Richard M. Scrowston
pg 63; DOI:
10.1039/P19770000063
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Protiodevinylation: the Schumm reaction of vinylporphyrins
Raymond Bonnett Ian H. Campion-Smith and Addis J. Page
pg 68; DOI:
10.1039/P19770000068
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Cyclization of diethyl 2-acetoacetyl-3-oxoglutarate anion generated in situ by the reaction of diethyl sodio-3-oxoglutarate with diketen
Eiji Suzuki Bunzo Katsuragawa and Shoji Inoue
pg 72; DOI:
10.1039/P19770000072
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Fragmentation of 2-(2-azidophenyl)pyridine and isomerisation of 553-pyrido[1,2-b]indazole
Joseph H. Boyer and Ching-Cheng Lai
pg 74; DOI:
10.1039/P19770000074
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N-amination and subsequent oxidation of imidazo[1,2-a]pyrimidines
David G. Doughty Edward E. Glover and Kenneth D. Vaughan
pg 78; DOI:
10.1039/P19770000078
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Strain factors in quinquecovalent phosphoranes. Sulphur-containing rings and six-membered rings
Stephen A. Bone Stuart Trippett and Peter J. Whittle
pg 80; DOI:
10.1039/P19770000080
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Reaction of phthalic anhydride with ethyl cyanoacetate: a route to the 2H-indeno[2,1 -c]pyridine-1,9-dione, 2H-indeno[2,1-c]pyridine-3,9-dione, 2H-indeno[2,1-c]pyridazine-3,9-dione, and indeno[2,1-c]pyran-1,9-dione systems
Andrew H. Renfrew and Stephen B. Bostock
pg 84; DOI:
10.1039/P19770000084
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Synthesis of naturally occurring 5-acetyl-2-isopropenylbenzofurans
Fred G. Schreiber and Robert Stevenson
pg 90; DOI:
10.1039/P19770000090
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Issue 2


Contents pages

pg P005; DOI:
10.1039/P197700FP005
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Allenes. Part 36. Synthesis of 2,4,5-trienamides as potential insecticides, by a Wittig reaction
Phyllis D. Landor Stephen R. Landor and Olwa Odyek
pg 93; DOI:
10.1039/P19770000093
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Photolysis of N-acyl-SS-diphenylsulphimides
Naomichi Furukawa Mitsuo Fukumura Takehiko Nishio and Shigeru Oae
pg 96; DOI:
10.1039/P19770000096
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N-methylated tetraphenylporphins
Hassan M. G. Al-Hazimi Anthony H. Jackson Alan W. Johnson and Manfred Winter
pg 98; DOI:
10.1039/P19770000098
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Triazines and related products. Part 18. Decomposition of 1,2,3-benzotriazines and related triazenes with sodium azide in acetic acid: a convenient route to azidoarenes
Andreas Gescher Malcolm F. G. Stevens and Colin P. Turnbull
pg 103; DOI:
10.1039/P19770000103
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Triazines and related products. Part 19. 4-Amino-2-[2-(piperidin-1-ylazo)phenyl]quinazoline and its analogues
Andreas Gescher Malcolm F. G. Stevens and Colin P. Turnbull
pg 107; DOI:
10.1039/P19770000107
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Reactions of terpenoids in strong acids. Part 2. Novel cyclisations of citronellol and the isomers of citral
Derek V. Banthorpe and Paul A. Boullier
pg 114; DOI:
10.1039/P19770000114
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Photochemical reactions of N-phenylacetyl and N-(2-iodophenylacetyl) derivatives of 1,2,3,3a,4,5-hexahydroindol-6-one
Hideo Iida Sakae Aoyagi and Chihiro Kibayashi
pg 120; DOI:
10.1039/P19770000120
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Selective alkylation of allyl phenyl sulphone. A novel synthesis of alk-2-enes
Diego Savoia Claudio Trombini and Achille Umani-Ronchi
pg 123; DOI:
10.1039/P19770000123
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Flavonoid synthesis based on photolysis of flavan-3-ols, 3-hydroxyflavanones, and 2-benzylbenzofuranones
Theunis G. Fourie Daneel Ferreira and David G. Roux
pg 125; DOI:
10.1039/P19770000125
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Novel conversions and coupling reactions of chalcones and their epoxides
Daneel Ferreira and David G. Roux
pg 134; DOI:
10.1039/P19770000134
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Cyclisation of arylpropiolyl chloro-oxalyl anhydrides: the chemistry of aryl(chloro)methylenetetrahydrofuran-2,4,5-triones and the X-ray crystal structure of a 3,4-methylenedioxybenzylidene representative
Michael J. Begley Leslie Crombie Roger G. Havard and Derek P. Reynolds
pg 138; DOI:
10.1039/P19770000138
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Thermal rearrangement of aryl(chloro)methylenetetrahydrofuran-2,4,5-triones: its mechanism and the chemistry of the resulting aroylchloro-maleic anhydrides
Leslie Crombie and Derek P. Reynolds
pg 146; DOI:
10.1039/P19770000146
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Diels–Alder reactions of polyfluorocyclohexa-1,3-dienes. Part 7. Reactions of perfluorotricyclo[6.2.2.0]dodeca-2,6,9-triene
W. James Feast Roger R. Hughes and W. Kenneth R. Musgrave
pg 152; DOI:
10.1039/P19770000152
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Biosynthesis of porphyrins and related macrocycles. Part 9. Biosynthesis of the corrin macrocycle of vitamin B12 including the stereochemistry of C-methylation in ring c
Alan R. Battersby Masataka Ihara Edward McDonald Janet R. Redfern (née Stephenson) and Bernard T. Golding
pg 158; DOI:
10.1039/P19770000158
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Biosynthesis of porphyrins and related macrocycles. Part 10. Vitamin B12: biochemical derivation of cobyrinic acid from uroporphyrinogen III, studies with the corresponding ring c methyl hepta-carboxylic porphyrinogen, and proof of seven intact methyl transfers
Alan R. Battersby Edward McDonald Roger Hollenstein Masataka Ihara Fumio Satoh and D. Clive Williams
pg 166; DOI:
10.1039/P19770000166
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Photochemical cyclisation of 2-iodostilbenes
Roy M. Letcher and Kum-Moon Wong
pg 178; DOI:
10.1039/P19770000178
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Sirodesmins A, B, C, and G, antiviral epipolythiopiperazine-2,5-diones of fungal origin: X-ray analysis of sirodesmin A diacetate
Philip J. Curtis David Greatbanks Barrie Hesp A. Forbes Cameron and Andrew A. Freer
pg 180; DOI:
10.1039/P19770000180
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Syntheses based on 1,2-secopenicillins. Part 4. A new tricyclic -lactam derivative
Michael J. Pearson
pg 189; DOI:
10.1039/P19770000189
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Synthesis and reactions of 1H-4,1,2-benzothiadiazines, and observations on the structure of hydrazonoyl sulphides
Darko J. Vukov Martin S. Gibson William E. Lee and Mary F. Richardson
pg 192; DOI:
10.1039/P19770000192
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Thermal acid-catalysed rearrangements of natural chrysanthemic acids
Dismas A. Otieno Gerald Pattenden and Christopher R. Popplestone
pg 196; DOI:
10.1039/P19770000196
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Ligands for the alkali metals. Part 3. Further examples of nitrogen-containing crown compounds
Joyce C. Lockhart and Maurice E. Thompson
pg 202; DOI:
10.1039/P19770000202
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Synthesis of L-cystine bis-t-butyl ester and its application to peptide synthesis
M. Joaquina S. A. Amaral M. Adelina Macedo and M. Isabel A. Oliveira
pg 205; DOI:
10.1039/P19770000205
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An approach to the synthesis of fujenoic acid
Tadahiro Kato Takeshi Suzuki Noboru Ototani Hideo Maeda Kenichi Yamada and (the late) Yoshio Kitahara
pg 206; DOI:
10.1039/P19770000206
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v-Triazolo[4,5-d]pyrimidines (8-azapurines). Part 18. Three new reactions for synthesizing 8-azapurinethiones from 4-amino-5-cyano-1,2,3-triazoles
Adrien Albert and Clara J. Lin
pg 210; DOI:
10.1039/P19770000210
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Preparation of macrocyclic compounds by thermal dimerization of 1,10-phenanthroline derivatives
Shojiro Ogawa
pg 214; DOI:
10.1039/P19770000214
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Issue 3


Contents pages

pg P007; DOI:
10.1039/P197700FP007
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Carbon-13 nuclear magnetic resonance spectroscopy of 1-tetralols and chroman-4-ols
Yasuhisa Senda Jun-ichi Ishiyama Shin Imaizumi and Kaoru Hanaya
pg 217; DOI:
10.1039/P19770000217
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The trans,anti,trans- and trans,syn,trans-isomers of dicyclohexyl-18-crown-6 and their complexes
Ian J. Burden Andrew C. Coxon J. Fraser Stoddart and Colin M. Wheatley
pg 220; DOI:
10.1039/P19770000220
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Reactions of alkenes with electrophilic iodine in tetramethylene sulphone–chloroform
Richard C. Cambie Wendy I. Noall Graeme J. Potter Peter S. Rutledge and Paul D. Woodgate
pg 226; DOI:
10.1039/P19770000226
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Reactions of silver(I) acetate–iodine and thallium(I) acetate–iodine with substituted cyclopropanes
Peter H. Atkinson Richard C. Cambie Graham Dixon Wendy I. Noall Peter S. Rutledge and Paul D. Woodgate
pg 230; DOI:
10.1039/P19770000230
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Photorearrangements of phenyloxazoles
Minoru Maeda and Masaharu Kojima
pg 239; DOI:
10.1039/P19770000239
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Reactions of 2,2-dimethyl-1,1-diphenylpropan-1-ol with acidic reagents: a reinvestigation of the dehydration products and isolation of a sulphonation product
Mrs. Heather Scott and Roy Shilton
pg 247; DOI:
10.1039/P19770000247
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Chemical transformations of the diterpene lactones momilactones A and B
Tadahiro Kato Hiroyasu Aizawa Mitsuaki Tsunakawa Nobuki Sasaki (the late) Yoshio Kitahara and Norindo Takahashi
pg 250; DOI:
10.1039/P19770000250
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Dynamic stereochemistry of imines and derivatives. Part 11. Synthesis and stereochemistry of (E)- and (Z)-nitrones
Johannes Bjørgo Derek R. Boyd David C. Neill and W. Brian Jennings
pg 254; DOI:
10.1039/P19770000254
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Microbiological hydroxylation. Part 22. Preparation of some bicyclic substrates containing 15–16 carbon atoms
A. Sydney Bailey Martin L. Gilpin and Sir Ewart R. H. Jones
pg 259; DOI:
10.1039/P19770000259
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Microbiological hydroxylation. Part 23. Bicyclic substrates for steroid-hydroxylating fungi
A. Sydney Bailey Martin L. Gilpin and Sir Ewart R. H. Jones
pg 265; DOI:
10.1039/P19770000265
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Cyclodepsipeptides from Beauveria bassiana Bals. Part 1. Beauverolides H and I
John F. Elsworth and John Frederick Grove
pg 270; DOI:
10.1039/P19770000270
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Apicophilicity of the ethylthio-group in trigonal bipyramidal phosphoranes
John Brierley Stuart Trippett and Michael W. White
pg 273; DOI:
10.1039/P19770000273
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Synthesis of phosphoranes by using N-chlorodi-isopropylamine
Stephen Antczak Stephen A. Bone John Brierley and Stuart Trippett
pg 278; DOI:
10.1039/P19770000278
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Kinetics and product orientation in oxidation of aldehyde 2,4-disubstituted phenylhydrazones by lead tetra-acetate; hydrazone azo tautomers
Richard N. Butler and William B. King
pg 282; DOI:
10.1039/P19770000282
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Elimination and addition reactions. Part 28. Nucleophilic addition–displacement reactions with allenic sulphonium salts
Brian S. Ellis Gwerydd Griffiths Peter D. Howes Charles J. M. Stirling and Brian R. Fishwick
pg 286; DOI:
10.1039/P19770000286
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Synthesis of oligopeptides having alternate L-leucyl and L-methionyl residues
Ryoichi Katakai and Yohko Nakayama
pg 292; DOI:
10.1039/P19770000292
PDF
Pseudomonic acid. Part 1. The structure of pseudomonic acid A, a novel antibiotic produced by Pseudomonas fluorescens
Sir Ernst B. Chain and Graham Mellows
pg 294; DOI:
10.1039/P19770000294
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Pseudomonic acid. Part 2. Biosynthesis of pseudomonic acid A
Timothy C. Feline Robert B. Jones Graham Mellows and Lawrence Phillips
pg 309; DOI:
10.1039/P19770000309
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Pseudomonic acid. Part 3. Structure of pseudomonic acid B
Sir Ernst B. Chain and Graham Mellows
pg 318; DOI:
10.1039/P19770000318
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Structures of three new diterpenoids from Ballota species
Giuseppe Savona Franco Piozzi James R. Hanson and Michael Siverns
pg 322; DOI:
10.1039/P19770000322
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Studies in terpenoid biosynthesis. Part 19. Formation of pimara-8(9),15-diene by Trichothecium roseum
Brian Dockerill and James R. Hanson
pg 324; DOI:
10.1039/P19770000324
PDF
N-oxides and related compounds. Part 55. 1-Pyridinio-4-pyridone cations and 1-pyridiniopyridinium dications: preparation and reactions
Michael P. Sammes Ho King Wah and Alan R. Katritzky
pg 327; DOI:
10.1039/P19770000327
PDF
Pyrroles and related compounds. Part 38. Porphobilinogen synthesis
George W. Kenner John Rimmer Kevin M. Smith and John F. Unsworth
pg 332; DOI:
10.1039/P19770000332
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Issue 4


Contents pages

pg P009; DOI:
10.1039/P197700FP009
PDF
Naturally occurring steroidal lactones with a 17-oriented side chain. Structure of withanolide E and related compounds
Erwin Glotter Arieh Abraham Gideon Günzberg and Isaac Kirson
pg 341; DOI:
10.1039/P19770000341
PDF
Reactions of N-nitrenes with allyl aryl sulphides: N-heteroarylsulphenamides
Robert S. Atkinson and Sami Bassili Awad
pg 346; DOI:
10.1039/P19770000346
PDF
Structures of virescenosides D and H, new metabolites of Acremonium luzulae(Fuckel) Gams
Nera Cagnoli-Bellavita Paolo Ceccherelli Mario Ribaldi Judith Polonsky Zoïa Baskevitch-Varon and Jeannette Varenne
pg 351; DOI:
10.1039/P19770000351
PDF
Ebenaceae extractives. Part 7. Use of hydroxy-proton shifts of juglone derivatives in structure elucidation
Terence J. Lillie and Oliver C. Musgrave
pg 355; DOI:
10.1039/P19770000355
PDF
Rhodium-catalysed isomerisation of some unsaturated organic substrates
Jean Andrieux Derek H. R. Barton and Henri Patin
pg 359; DOI:
10.1039/P19770000359
PDF
Conformational studies on the bicyclo[3.3.2]decane system
Martin Doyle Russell Hafter and William Parker
pg 364; DOI:
10.1039/P19770000364
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The halogen–dimethyl sulphoxide system as an oxidizing reagent; a convenient method for preparation of diaryl di- and tri-ketones
Naomichi Furukawa Takeshi Akasaka Tetsuo Aida and Shigeru Oae
pg 372; DOI:
10.1039/P19770000372
PDF
Studies on the syntheses of heterocyclic compounds. Part 678. Photoracemisation and photoepimerisation of the phthalidylisoquinoline alkaloids (–)--narcotine and (–)--hydrastine
Tetsuji Kametani Hitoshi Inoue Toshio Honda Tsutomu Sugahara and Keiichiro Fukumoto
pg 374; DOI:
10.1039/P19770000374
PDF
Studies on the syntheses of heterocyclic compounds. Part 679. A stereoselective total synthesis of ()-ophiocarpine; a simple route to 13-hydroxyberbines
Tetsuji Kametani Hiroo Matsumoto Yoshinari Satoh Hideo Nemoto and Keiichiro Fukumoto
pg 376; DOI:
10.1039/P19770000376
PDF
Studies on the syntheses of heterocyclic compounds. Part 680. Abnormal formation of aporphine derivatives by Grewe cyclisation
Tetsuji Kametani Tsuneo Uryu and Keiichiro Fukumoto
pg 383; DOI:
10.1039/P19770000383
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Studies on the syntheses of heterocyclic compounds. Part 681. A novel alkylation in the 4-position of isoquinoline derivatives
Tetsuji Kametani Hideo Nemoto Mie Takeuchi Mitsuhiro Takeshita and Keiichiro Fukumoto
pg 386; DOI:
10.1039/P19770000386
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Studies on the syntheses of heterocyclic compounds. Part 682. Six new isoquinoline alkaloids from Corydalis ochotensis var. raddeana
Tetsuji Kametani Makoto Takemura Masataka Ihara and Keiichiro Fukumoto
pg 390; DOI:
10.1039/P19770000390
PDF
Studies on the syntheses of heterocyclic compounds. Part 683. Stevens rearrangement of berbine methiodides by sodium bis-(2-methoxyethoxy)aluminium hydride
Tetsuji Kametani Akira Ujiie Shyh-Pyng Huang Masataka Ihara and Keiichiro Fukumoto
pg 394; DOI:
10.1039/P19770000394
PDF
New chromones from Spathelia sorbifolia L. (Rutaceae); synthesis of the benzo[1,2-b:3,4-b]dipyranone sorbifolin
David R. Taylor John M. Warner and John A. Wright
pg 397; DOI:
10.1039/P19770000397
PDF
The hydroquinone terpenoids of Cordia alliodora
Gary D. Manners and Leonard Jurd
pg 405; DOI:
10.1039/P19770000405
PDF
Photochemical behaviour of bicyclo[6.3.1]dodec-1(11)-en-10-one. Crystal and molecular structure of 9,11-dibromotricyclo[6.3.1.0]-dodecan-10-one
Bruno Gioia Alessandro Marchesini Giovanni Dario Andreetti Gabriele Bocelli and Paolo Sgarabotto
pg 410; DOI:
10.1039/P19770000410
PDF
-Complexes as biochemical probes. Part 1. -Complex formation by 7-methoxy-4-nitrobenzofurazan 1-oxide
Erwin Buncel Noemi Chuaqui-Offermanns and Albert R. Norris
pg 415; DOI:
10.1039/P19770000415
PDF
Chemical investigation of ceylonese plants. Part 23. Extractives of Hydnocarpus octandra Thw. (Flacourtiaceae); isolation and characterisation of six new triterpenoids
Sarath P. Gunasekera and M. Uvais S. Sultanbawa
pg 418; DOI:
10.1039/P19770000418
PDF
Synthesis of neobanone, a 12a-methoxy-rotenoid
Maria E. Oberholzer Gerhardus J. H. Rall and David G. Roux
pg 423; DOI:
10.1039/P19770000423
PDF
Reactions of steroidal 8,9- and 8,14-epoxy-7-ketones with acetic acid
Mario Anastasia Giuliana Cighetti and Ada Manzocchi Soave
pg 427; DOI:
10.1039/P19770000427
PDF
Syntheses of 1,3,3-trimethyl-2-oxabicyclo[2.2.2]oct-5-ene (2,3-didehydro-1,8-cineole), 6,6-dimethyl-2-methylene-7-oxabicyclo[3.2.1]octane (isopinol), 2,6,6-trimethyl-7-oxabicyclo[3.2.1]oct-2-ene (pinol), and 1-(3-lsopropylidenecyclopentyl)ethanone (pinolone) from hydroxy- and bromo-derivatives of cineole
Francesco Bondavalli Pietro Schenone Silvia Lanteri and Angelo Ranise
pg 430; DOI:
10.1039/P19770000430
PDF
Isolation and identification of two phenolic ketones and a chromone from Dysophylla stellata Benth.
Balawant S. Joshi and Kongovi R. Ravindranath
pg 433; DOI:
10.1039/P19770000433
PDF
Relative apicophilicities of alkyl and aryl groups in quinquecovalent phosphoranes
Stephen A. Bone Stuart Trippett and Peter J. Whittle
pg 437; DOI:
10.1039/P19770000437
PDF
Dihydropteroate synthase: purification by affinity chromatography and mechanism of action
Colin J. Suckling John R. Sweeney and Hamish C. S. Wood
pg 439; DOI:
10.1039/P19770000439
PDF
Reduction of nitro-compounds
Ian D. Entwistle Alan E. Jackson Robert A. W. Johnstone and Robert P. Telford
pg 443; DOI:
10.1039/P19770000443
PDF
The phosphotriester approach to oligonucleotide synthesis: preparation of oligo- and poly-thymidylic acids
René Arentzen and Colin B. Reese
pg 445; DOI:
10.1039/P19770000445
PDF
Stability of arenide ions. Cleavage of unsymmetrical diaryl ketones with potassium t-butoxide
Jerry March and Walter Plankl
pg 460; DOI:
10.1039/P19770000460
PDF

Issue 5


Contents pages

pg P011; DOI:
10.1039/P197700FP011
PDF
Synthesis and reactions of the 1H-imidazo[1,2-a]pyrrolo[3,2-e]pyridine system
Keith C. C. Bancroft Terence J. Ward and Kevan Brown
pg 465; DOI:
10.1039/P19770000465
PDF
Novel tetracycline analogues. Part 1. Development of a potential synthetic route
Denis S. Ireland and Jeffrey R. Brown
pg 467; DOI:
10.1039/P19770000467
PDF
Benzofurazan N-oxides as synthetic precursors. Part 2. Conversion of benzofurazan N-oxides into 2H-benzimidazoles and some unusual reactions of 2H-benzimidazoles
D. W. S. Latham O. Meth-Cohn H. Suschitzky and J. A. L. Herbert
pg 470; DOI:
10.1039/P19770000470
PDF
Benzofurazan N-oxides as synthetic precursors. Part 3. Acid-catalysed cyclisation of NN-dialkyl-N-(o-nitrophenyl)hydrazines
David W. S. Latham Otto Meth-Cohn and Hans Suschitzky
pg 478; DOI:
10.1039/P19770000478
PDF
Chemical investigation of ceylonese plants. Part 22. Extractives of Trichadenia zeylanica Thw. (Flacourtiaceae); isolation and structures of six new triterpenoids containing the friedelane skeleton
Sarath P. Gunasekera and M. Uvais S. Sultanbawa
pg 483; DOI:
10.1039/P19770000483
PDF
Transfer hydrogenation; a convenient method for removal of some commonly used protecting groups in peptide synthesis
Gattadahalli M. Anantharamaiah and Kadlebal M. Sivanandaiah
pg 490; DOI:
10.1039/P19770000490
PDF
13C nuclear magnetic resonance spectroscopy of vanillin derivatives
Anton F. Erasmuson Robert J. Ferrier Nidia C. Franca Hugo E. Gottlieb and Ernest Wenkert
pg 492; DOI:
10.1039/P19770000492
PDF
Ring opening of a 4,9-dioxa-2-azabicyclo[4.2.1]nonane-3-thione
Vinko kari Marijan Hohnjec and Djurdja kari
pg 494; DOI:
10.1039/P19770000494
PDF
The structure of ballotenol, a new diterpenoid from Ballota nigra
Giuseppe Savona Franco Piozzi James R. Hanson and Michael Siverns
pg 497; DOI:
10.1039/P19770000497
PDF
Preparation of androsta-2,5-dien-4-ones
James R. Hanson David Raines and Harry Wadsworth
pg 499; DOI:
10.1039/P19770000499
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Bromination of ketones in the presence of epoxides as a method for regiospecific synthesis of bromo-ketones
Vincenzo Calò Luigi Lopez and Giovanni Pesce
pg 501; DOI:
10.1039/P19770000501
PDF
Annelated tropones. Part 3. Photochemistry of some cyclohepta[b]-thiophen-4-ones
Gurnos Jones and Michael J. Robinson
pg 505; DOI:
10.1039/P19770000505
PDF
Triterpenoids of Aglaia odorata. Configuration of trisubstituted epoxides
Robin B. Boar and Kathleen Damps
pg 510; DOI:
10.1039/P19770000510
PDF
Reactions of 2-chloro-NN-diethyl-1,1,2-trifluoroethylamine with alcohols. Part 2. Bridgehead fluorination of gibberellins
Robert E. Banks and Brian E. Cross
pg 512; DOI:
10.1039/P19770000512
PDF
Synthesis and photolysis of some lanostanes unsaturated in rings B and C. Characterisation of the stable dithiet tautomer of a dithio-o-quinone
Robin B. Boar David W. Hawkins James F. McGhie and Derek H. R. Barton
pg 515; DOI:
10.1039/P19770000515
PDF
Condensed cyclic and bridged-ring systems. Part 6. Stereochemically defined synthesis of ()-3-methoxy-17,18,19,20-tetranor-B-homophylloclada-1(10),2,4-triene-16-one through intramolecular alkylation of a -unsaturated -diazomethyl ketone
Usha R. Ghatak and Jayanta K. Ray
pg 518; DOI:
10.1039/P19770000518
PDF
Synthetic studies with carbonates. Part 10. Reactions of ethylene carbonate with some active methylene compounds catalysed by quaternary ammonium or alkali metal halides
Yoshiharu Ishido Hideo Tsutsumi and Shigeru Inaba
pg 521; DOI:
10.1039/P19770000521
PDF
The Prvost reaction with 5-androst-2-ene
Richard C. Cambie Graeme J. Potter Peter S. Rutledge and Paul D. Woodgate
pg 530; DOI:
10.1039/P19770000530
PDF
Pyrrolizidine alkaloid analogues. Preparation of semisynthetic esters of retronecine
W. Michael Hoskins and David H. G. Crout
pg 538; DOI:
10.1039/P19770000538
PDF
Absolute configuration of 2,3-dihydroxy-3-methylpentanoic acid, an intermediate in the biosynthesis of isoleucine, and its identity with the esterifying acid of the pyrrolizidine alkaloid strigosine
David H. G. Crout and David Whitehouse
pg 544; DOI:
10.1039/P19770000544
PDF
Regioselectivity and control in alkene formation from a carbonium ion after diphenylphosphinoyl migration
Alan H. Davidson Ian Fleming J. Ian Grayson Andrew Pearce Roger L. Snowden and Stuart Warren
pg 550; DOI:
10.1039/P19770000550
PDF
Action of nucleophiles on tetramethylthiuram monosulphide
Trevor M. Kitson
pg 565; DOI:
10.1039/P19770000565
PDF
Experiments on the synthesis of tetracycline. Part 15. Oxidation of phenols and ring A model phenols to o-hydroxy-dienones with benzeneseleninic anhydride
Derek H. R. Barton Steven V. Ley Philip D. Magnus and Moshe N. Rosenfeld
pg 567; DOI:
10.1039/P19770000567
PDF
Stereoselectivity in the epoxidation of -unsaturated carboxylic acids
Stephen G. Davies and Gordon H. Whitham
pg 572; DOI:
10.1039/P19770000572
PDF
Asymmetric synthesis. Part 5. Asymmetric reduction of phenyl trifluoromethyl ketone with chiral alkoxy-aluminium and -magnesium halides
Dhanonjoy Nasipuri and Pranab K. Bhattacharya
pg 576; DOI:
10.1039/P19770000576
PDF
Studies on the syntheses of heterocyclic compounds. Part 687. Asymmetric synthesis of salsolidine
Tetsuji Kametani and Tadashi Okawara
pg 579; DOI:
10.1039/P19770000579
PDF
Synthesis of 2-(p-nitrophenoxy)ethylamine and its N-alkyl, N-aryl, and 1,1-dimethyl derivatives
Anthony C. Knipe Narayan Sridhar and Joseph Lound-Keast
pg 581; DOI:
10.1039/P19770000581
PDF
Oxidation of phenols. Part 5. Oxidation of 2-allyl-4-t-butylphenol
David T. Dalgleish Norman P. Forrest Derek C. Nonhebel and Peter L. Pauson
pg 584; DOI:
10.1039/P19770000584
PDF
Malabaricones A–D, novel diarylnonanoids from Myristica malabarica Lam (Myristicaceae)
Kozhiparambil K. Purushothaman Ayyappath Sarada and Joseph D. Connolly
pg 587; DOI:
10.1039/P19770000587
PDF

Issue 6


Contents pages

pg P013; DOI:
10.1039/P197700FP013
PDF
Mononuclear heterocyclic rearrangements. Part 10. Rearrangements in the 1,2,5-oxadiazole series
Michele Ruccia Nicolò Vivona Giuseppe Cusmano and Gabriella Macaluso
pg 589; DOI:
10.1039/P19770000589
PDF
13C nuclear magnetic resonance spectra and biosynthetic studies of xanthomegnin and related pigments from Aspergillus sulphureus and melleus
Thomas J. Simpson
pg 592; DOI:
10.1039/P19770000592
PDF
Synthesis of peptides containing 1,2,3,4-tetrahydroquinoline-2-carboxylic acid. Part 1. Absolute configurations of 1,2,3,4-tetrahydroquinoline-2-carboxylic acids and 2-substituted 1,2,3,4-tetrahydroquinolines
Mario Paglialunga Paradisi and Aurelio Romeo
pg 596; DOI:
10.1039/P19770000596
PDF
Preparation of some isoindolo[2,1-f]phenanthridine derivatives
Munir Ahmed and John M. Vernon
pg 601; DOI:
10.1039/P19770000601
PDF
Hydrolysis of (N-aryl)alkylphenylphosphinic amides in acidic solution: influence of different P-alkyl groups, including cyclopropyl, and of substituents in the N-aryl group
Martin J. P. Harger
pg 605; DOI:
10.1039/P19770000605
PDF
Terpenoids. Part 39. Total synthesis of gibberellins A15 and A37
Eiichi Fujita Manabu Node and Hitoshi Hori
pg 611; DOI:
10.1039/P19770000611
PDF
Photolysis of 5-iodopyrimidines in benzene or heteroarenes; a convenient route to 5-phenyl- and 5-heteroaryl-pyrimidines
David W. Allen David J. Buckland Barrie G. Hutley A. Christopher Oades and J. Bryan Turner
pg 621; DOI:
10.1039/P19770000621
PDF
Alkylation of 3,4-methylenedioxyphenol with 1-bromo-3-methylbut-2-ene and catalytic rearrangement of the resulting ethers
Paolo Piccardi Silvana Marcaletti Ennio Bianchini and Luigi Abis
pg 624; DOI:
10.1039/P19770000624
PDF
Crown ethers as catalysts of fluoride-anion-mediated reactions in peptide synthesis. Part 1. Protection of tryptophan by benzyloxycarbonyl and 2,4-dichlorobenzyloxycarbonyl groups
Yakir S. Klausner and Michael Chorev
pg 627; DOI:
10.1039/P19770000627
PDF
Photochemical transformations. Part 34. Structures of the toxisterols2
Anthony G. M. Barrett Derek H. R. Barton Richard A. Russell and David A. Widdowson
pg 631; DOI:
10.1039/P19770000631
PDF
Synthesis of derivatives of methyl 2,6-dideoxy-4-O-methyl--D-ribo-hexopyranoside: on the structure of variose
John S. Brimacombe Annalee S. Mengech and Leslie C. N. Tucker
pg 643; DOI:
10.1039/P19770000643
PDF
Formation of optically active 1,2,4-triazoles from the reactions of optically active N-arylmandelamidrazones with trialkyl ortho esters or aldehydes
John K. Fraser Douglas G. Neilson Kathleen M. Watson and James W. M. Heatlie
pg 646; DOI:
10.1039/P19770000646
PDF
Synthesis and electron spin resonance of 3-oxy-1,3-diazacyclohexene 1-oxide (1,3-nitrone–nitroxide) radicals
Siobhan Ni Ghriofa Raphael Darcy and Michael Conlon
pg 651; DOI:
10.1039/P19770000651
PDF
Caldariellaquinone, a unique benzo[b]thiophen-4,7-quinone from Caldariella acidophila, an extremely thermophilic and acidophilic bacterium
Mario De Rosa Salvatore De Rosa Agata Gambacorta Luigi Minale Ronald H. Thomson and Roger D. Worthington
pg 653; DOI:
10.1039/P19770000653
PDF
Partial protection of carbohydrate derivatives. Part 1. Specific N-debenzoylation of fully benzoylated adenosine and cytidine with phenols and alcohols; active N-benzoyl groups
Yoshiharu Ishido Nobuo Nakazaki and Nobuo Sakairi
pg 657; DOI:
10.1039/P19770000657
PDF
Base-catalysed Neber-type rearrangement of glucosinolates [1-(-D-glucosylthio)-N-(sulphonato-oxy)alkylideneamines]
Palle Friis Peder Olesen Larsen and Carl Erik Olsen
pg 661; DOI:
10.1039/P19770000661
PDF
Reactions of a mono- and a tri-substituted epoxide with some simple and -substituted primary amines; novel examples of electrophilic anchimeric assistance
David R. Burfield Seng-neon Gan and Roger H. Smithers
pg 666; DOI:
10.1039/P19770000666
PDF
Studies in azole chemistry. Part 2. Nitration of 1,4,5-trimethylimidazole 3-oxide and 1-methylpyrazole 2-oxide, and some reactions of the products
Ian J. Ferguson Kenneth Schofield James W. Barnett and M. Ross Grimmett
pg 672; DOI:
10.1039/P19770000672
PDF
Chlorination and chloroiodination of acetylenes with copper(II) chloride
Sakae Uemura Hajime Okazaki Akira Onoe and Masaya Okano
pg 676; DOI:
10.1039/P19770000676
PDF
Stability of the dilithium salts formed by the reaction of organolithium derivatives with lithium salts of aromatic carboxylic acids
Philip Hodge Gordon M. Perry and Paul Yates
pg 680; DOI:
10.1039/P19770000680
PDF
Isolation and structure of coprine, the in vivo aldehyde dehydrogenase inhibitor in Coprinus atramentarius; syntheses of coprine and related cyclopropanone derivatives
Per Lindberg Rolf Bergman and Börje Wickberg
pg 684; DOI:
10.1039/P19770000684
PDF
Reactions of 6a,11a-dihydro-6H-benzofuro[3,2-c]benzopyran
Peter J. M. Gunning Philip J. Kavanagh Mary J. Meegan and Dervilla M. X. Donnelly
pg 691; DOI:
10.1039/P19770000691
PDF
Steric limits to ester alkylation; synthesis of highly hindered esters via hexamethylphosphoramide-favoured enolization
John Anthony MacPhee and Jacques-Emile Dubois
pg 694; DOI:
10.1039/P19770000694
PDF
Conversion of bicyclic -dichlorocyclobutanones into monocyclic -formyl esters and bicyclic cyclopropanes with silver tetrafluoroborate
Ahmed K. Yagoub George M. Iskander and Frank Stansfield
pg 697; DOI:
10.1039/P19770000697
PDF
Synthesis of cholestanes containing an oxygenated 14-methyl group
Mario Anastasia Alberto Fiecchi Giuliana Cighetti and Giovanni Galli
pg 700; DOI:
10.1039/P19770000700
PDF
Synthesis of doryanine and related isoquinolones and isocoumarins
Vasant H. Belgaonkar and Ramesh N. Usgaonkar
pg 702; DOI:
10.1039/P19770000702
PDF
Biosynthesis of boldine (1,10-dimethoxy-6a-aporphine-2,9-diol)
Dewan S. Bhakuni Shobha Tewari and Randhir S. Kapil
pg 706; DOI:
10.1039/P19770000706
PDF
Resolution of 2,3-dihydrosqualene-2,3-diol, 10,11-dihydro-10,11-dihydroxyfarnesyl benzoate, and 6,7-dihydro-6,7-dihydroxygeranyl benzoate. Synthesis of (3R)- and (3S)-2,3-epoxy-2,3-dihydrosqualene
Robin B. Boar and Kathleen Damps
pg 709; DOI:
10.1039/P19770000709
PDF

Issue 7


Contents pages

pg P015; DOI:
10.1039/P197700FP015
PDF
The structures of five new didehydropeptides related to neoechinulin, isolated from Aspergillus amstelodami
Rosangela Marchelli Arnaldo Dossena Andrea Pochini and Emanuele Dradi
pg 713; DOI:
10.1039/P19770000713
PDF
Crystal structure of higenamine [1,2,3,4-tetrahydro-1-(4-hydroxybenzyl)isoquinoline-6,7-diol] hydrobromide
Norio Masaki Hisao Iizuka Masami Yokota and Akio Ochiai
pg 717; DOI:
10.1039/P19770000717
PDF
Reaction of ethyl diazoacetate with cobalt porphyrins. Part 2
Alan W. Johnson and David Ward
pg 720; DOI:
10.1039/P19770000720
PDF
Hydroxylation of 4-steroids by osmium tetraoxide; stereochemistry and substituent effects
James R. Bull and Jan Floor
pg 724; DOI:
10.1039/P19770000724
PDF
Dehydrohalogenation of some tetrahalogenobicyclo[4.1.0]hept-3-enes. Formation and decomposition of 1,1-dihalogenocyclopropabenzenes
Brian Halton Paul J. Milsom and Anthony D. Woolhouse
pg 731; DOI:
10.1039/P19770000731
PDF
Replacement reactions of 1,1-dichloro-2,5-diphenylcyclopropabenzene with organometallic reagents
Brian Halton Anthony D. Woolhouse and Paul J. Milsom
pg 735; DOI:
10.1039/P19770000735
PDF
Extractives of Polygala. Part 5. New trioxygenated xanthones of P. arillata
Shibnath Ghosal Shanta Banerjee (née Chakrabarti) Rama Ballava P. S. Chauhan and Radhey S. Srivastava
pg 740; DOI:
10.1039/P19770000740
PDF
Synthesis of C-glycosyl compounds. Part 1. Reaction of ethyl isocyanoacetate with 2,3:5,6-di-O-isopropylidene-D-mannono-1,4-lactone
Richard H. Hall Karl Bischofberger Stephen J. Eitelman and Amor Jordaan
pg 743; DOI:
10.1039/P19770000743
PDF
Zirconium-hydroxide-mediated alkaline hydrolysis of phosphate esters
John F. Kennedy S. Alan Barker and John D. Humphreys
pg 753; DOI:
10.1039/P19770000753
PDF
Aminoacyl and dihydro-derivatives of isocytidine and isocytosine
Vinko kari Goran Laan and Djurdja kari
pg 757; DOI:
10.1039/P19770000757
PDF
Synthesis of C-nucleosides. Part 14. 5(3)-Glycosyl-1,2,4-triazole-3(5) carboxamides as analogues of ribavirin
T. Huynh-Dinh J. Igolen E. Bisagni (the late) J. P. Marquet and A. Civier
pg 761; DOI:
10.1039/P19770000761
PDF
Synthesis of pyrazolo[3,4-d]pyrimidines by intramolecular cycloaddition of azahexatrienes
Fumio Yoneda Tomohisa Nagamatsu Tetsuya Nagamura and Keitaro Senga
pg 765; DOI:
10.1039/P19770000765
PDF
Macrobicyclic polyethers with bridgehead carbon atoms
Andrew C. Coxon and J. Fraser Stoddart
pg 767; DOI:
10.1039/P19770000767
PDF
1,6,13,18,25,30-Hexaoxa[6.6.6](1,3,5)cyclophane. Attempted synthesis of a [4]cryptand
W. David Curtis J. Fraser Stoddart and Graham H. Jones
pg 785; DOI:
10.1039/P19770000785
PDF
Nitrogen bridgehead compounds. Part 4. 1
István Hermecz Zoltán Mészáros Lelle Vasvári-Debreczy Ágnes Horváth Gábor Horváth and Mariann Pongor-Csákvári
pg 789; DOI:
10.1039/P19770000789
PDF
1-Oxo-steroids. Part 2. Model studies for the synthesis of the withanolides
Martin Weissenberg David Lavie and Erwin Glotter
pg 795; DOI:
10.1039/P19770000795
PDF
Synthesis of pterofuran and vignafuran
Richard P. Duffley and Robert Stevenson
pg 802; DOI:
10.1039/P19770000802
PDF

Issue 8


Contents pages

pg P017; DOI:
10.1039/P197700FP017
PDF
Unsaturated steroids. Part 2. A novel route to anthrasteroids: X-ray crystal structure of 1(10
Nigel Bosworth Alice Emke John M. Midgley Christopher J. Moore W. Basil Whalley George Ferguson and Wayne C. Marsh
pg 805; DOI:
10.1039/P19770000805
PDF
Unsaturated steroids. Part 3. Synthesis of steroidal 22,24(28)-dienes, ergosta-5,7,22,24(28)-tetraen-3-ol, and cholesta-5,7,22-trien-3-ol
Alex B. Garry John M. Midgley W. Basil Whalley and Brian J. Wilkins
pg 809; DOI:
10.1039/P19770000809
PDF
Unsaturated steroids. Part 4. Some steroidal hydroxy-4,4-dimethyl-5,7-dienes and 4,4-dimethyl-5,7,14(15)-trienes
Jitka Brynjolffssen John M. Midgley and W. Basil Whalley
pg 812; DOI:
10.1039/P19770000812
PDF
Unsaturated steroids. Part 5. Synthesis of 4-methylcholest-8(9)-en-3-ol
Peter J. Hylands John M. Midgley Christopher Smith Adrian F. A. Wallis and W. Basil Whalley
pg 817; DOI:
10.1039/P19770000817
PDF
Unsaturated steroids. Part 6. A route to cholesta-5,7-diene-1,3-diol; preparation of steroidal 4,6,8(14)-trienes
Alice Emke David Hands John M. Midgley W. Basil Whalley and Riaz Ahmad
pg 820; DOI:
10.1039/P19770000820
PDF
Unsaturated steroids. Part 7. A simple synthesis of 22,23-dihydroergosterol
David J. Curry John M. Midgley Sai L. Leung Robert Watt and W. Basil Whalley
pg 822; DOI:
10.1039/P19770000822
PDF
Conformational studies. Part 2. Synthesis of 17-hydroxy-4,4-dimethyl-5-androstan-3-one, and of the 19-nor-analogue
John M. Midgley W. Basil Whalley Patricia A. Dodson Gerald F. Katekar and Bruce A. Lodge
pg 823; DOI:
10.1039/P19770000823
PDF
Conformational studies. Part 3. Synthesis of some alicyclic dienes
Michael H. Barnes and W. Basil Whalley
pg 828; DOI:
10.1039/P19770000828
PDF
Conformational studies. Part 4. Some reactions of spiro[cholest-4-ene-6-spirocyclopropane]-3-one
Adrian F. A. Wallis and W. Basil Whalley
pg 832; DOI:
10.1039/P19770000832
PDF
Conformational studies. Part 5. Functionalisation of methyl groups in 4,4-dimethyl steroids
John M. Midgley John E. Parkin and W. Basil Whalley
pg 834; DOI:
10.1039/P19770000834
PDF
Studies of heterocyclic compounds. Part 21. Reactions of 1-aryl-6,6a-dithia-1,2-diazapentalenes with electrophiles
Robert M. Christie and David H. Reid
pg 848; DOI:
10.1039/P19770000848
PDF
Studies of heterocyclic compounds. Part 22. Reactions of 1,6-dioxa-6a4-thiapentalenes
David H. Reid and Robert G. Webster
pg 854; DOI:
10.1039/P19770000854
PDF
Transannular hydride shifts; the solvolytic behaviour of bicyclo[3.3.2]-decan-3-exo-yl toluene-p-sulphonate
Martin Doyle and William Parker
pg 858; DOI:
10.1039/P19770000858
PDF
Nucleophilic character of alkyl radicals. Part 15. Selective homolytic alkylation of quinoxaline by N-chloro-amines; influence of medium acidity
T. Caronna A. Citterio T. Crolla and F. Minisci
pg 865; DOI:
10.1039/P19770000865
PDF
A simple procedure for the elaboration of carbonyl compounds into homologous alkynes
Ernest W. Colvin and Brendan J. Hamill
pg 869; DOI:
10.1039/P19770000869
PDF
Reaction of chlorosulphonyl isocyanate with 1,3-dienes. Control of 1,2- and 1,4-addition pathways and the synthesis of aza- and oxa-bicyclic systems
J. R. Malpass and N. J. Tweddle
pg 874; DOI:
10.1039/P19770000874
PDF
Reactions of nitrobenzothiazoles with Grignard reagents. Orientation of alkylation with respect to the nitro-group position
Giuseppe Bartoli Rino Leardini Maria Lelli and Goffredo Rosini
pg 884; DOI:
10.1039/P19770000884
PDF
High-yield syntheses of dilithio-derivatives of furan, thiophen, N-methylpyrrole, 3-methylfuran, and 3-methylthiophen. Application of the method to 2-methylfuran, 2-methylthiophen, 2,5-dimethylfuran, 2,5-dimethylthiophen, benzo[b]furan, benzo[b]thiophen, pyrrole, and indole
Derek J. Chadwick and Charles Willbe
pg 887; DOI:
10.1039/P19770000887
PDF
D-homo-steroids. Part 6. 1-Acetyl-2,2-dimethylcyclopentanol: a monocyclic model for D-homoannulation of 17-hydroxypregnan-20-ones
David N. Kirk and Conor R. McHugh
pg 893; DOI:
10.1039/P19770000893
PDF
Six new triterpenoids and other triterpenoids and steroids from three Quercus species of Hong Kong
Wai-Haan Hui and Man-Moon Li
pg 897; DOI:
10.1039/P19770000897
PDF
Reactions of N-sulphinylamines and di-iminosulphur derivatives with acylketens
Toru Minami Yasuhisa Yamauchi Yoshiki Ohshiro Toshio Agawa Sinji Murai and Noboru Sonoda
pg 904; DOI:
10.1039/P19770000904
PDF
Preparation and reactions of 2-amino- and 2-acetamido-4-methylthiazole-5-carbohydrazides: revision of the literature
G. Denis Meakins and Charles Willbe
pg 908; DOI:
10.1039/P19770000908
PDF
Elimination and addition reactions. Part 29. Ylide rearrangement in adducts from allenic sulphonium salts and malonic esters
Gwerydd Griffiths Peter D. Howes and Charles J. M. Stirling
pg 912; DOI:
10.1039/P19770000912
PDF
Some reactions of unsaturated sulphur–nitrogen heterocycles with nucleophilic substrates
Derek H. R. Barton and William A. Bubb
pg 916; DOI:
10.1039/P19770000916
PDF
Chemistry of hindered amines: synthesis and properties of di-t-butylamine and related compounds
Thomas G. Back and Derek H. R. Barton
pg 924; DOI:
10.1039/P19770000924
PDF
Photoinduced transformations. Part 33. Mechanism of photoinduced rearrangement of a (22S,25S)-N-acetylveratr-13(17)-enin-11-yl nitrite, a fused cyclopentyl nitrite, to a nitrone
Hiroshi Suginome Terutoshi Mizuguchi Saho Honda and Tadashi Masamune
pg 927; DOI:
10.1039/P19770000927
PDF
Reactivity of p-bromophenyl vinyl sulphone towards the morpholine enamine from 4a-methyl-trans-decalin-2-one. Crystal and molecular structure of 1-(2-p-bromophenylsulphonylethyl)-4a-methyl-2-morpholino-2-trans-octalin
Mirella Forchiassin Amerigo Risaliti Claudio Russo Nevina Bresciani Pahor and Mario Calligaris
pg 935; DOI:
10.1039/P19770000935
PDF
Cycloadditions of diphenylnitrilimine with tropone and with tricarbonyltroponeiron. Thermal [1,5] sigmatropic rearrangements of the [6s+4s] cycloadducts of 1,3-dipoles with tropone
Milena Bonadeo Carlo De Micheli and Remo Gandolfi
pg 939; DOI:
10.1039/P19770000939
PDF

Issue 9


Contents pages

pg P019; DOI:
10.1039/P197700FP019
PDF
Mechanism of ester formation during decarboxylation with t-butyl hypochlorite and iodine
Michael R. Britten-Kelly André Goosen Janet Lovelock and André Scheffer
pg 945; DOI:
10.1039/P19770000945
PDF
Synthesis of tachrosin, ()-stachyoidin, and ()-tephrodin, prenylflavonoids of novel type from Tephrosia polystachyoides
Sándor Antus Loránd Farkas Mihály Nógrádi and Ferenc Boross
pg 948; DOI:
10.1039/P19770000948
PDF
Synthesis of isoquinoline derivatives related to the endo-6,14-ethenotetrahydrothebaines. Part 2
Trevor A. Crabb and John R. Wilkinson
pg 953; DOI:
10.1039/P19770000953
PDF
Nitrogen heterocycles. Part 6. Conversion of 3-(-bromobenzylidene)-2-phenethylphthalimidine into pyrrole and benzazepine derivatives; base-catalysed rearrangement and photolysis of 3-(-bromobenzylidene)phthalimidine
Antonio Marsili Valeric Scartoni Ivano Morelli and Paola Pierangeli
pg 959; DOI:
10.1039/P19770000959
PDF
Reaction of dehydrodithizone with tetraphenylcyclopentadienone. X-Ray crystal structures of a stable 1,5-dipole, azobenzene N-(cis-3a,6a-dihydro-4-oxo-3a,5,6,6a-tetraphenyl-4H-cyclopentathiazol-2-yl)-imide, and of cis-3a,6a-dihydro-3a,5,6,6a-tetraphenyl-2-phenylazo-4H-cyclopentathiazol-4-one
Gerhard V. Boyd Timothy Norris and Peter F. Lindley
pg 965; DOI:
10.1039/P19770000965
PDF
Thermally induced isomerisation of isoxazol-5-ylhydrazines
Giorgio Adembri Alfredo Camparini Fabio Ponticelli and Piero Tedeschi
pg 971; DOI:
10.1039/P19770000971
PDF
o-Quinonoid compounds. Part 12. Diels–Alder additions to 1,3-di-methylcyclopenta[I]phenanthren-2-one
David W. Jones
pg 980; DOI:
10.1039/P19770000980
PDF
Reduction of 1-oxo-steroids by sodium borohydride
Martin Weissenberg and Erwin Glotter
pg 988; DOI:
10.1039/P19770000988
PDF
Photochemistry of sulphur compounds related to the 1,2-dithiole system. Part 6. Photoisomerization of 1,6,6a4-trithiapentalenes
Carl Th. Pedersen and Christian Lohse
pg 994; DOI:
10.1039/P19770000994
PDF
Purines, pyrimidines, and imidazoles. Part 45. Stereospecific syntheses of some 1-D-ribofuranosyl- and 1-D-xylofuranosyl-uracil derivatives
Roy Lofthouse Gordon Shaw Peter S. Thomas Grahame Mackenzie David H. Robinson and Peter W. Rugg
pg 997; DOI:
10.1039/P19770000997
PDF
Synthesis and reactions of 7,8-dihydro-8-methylpterin and 9-methylguanine 7-oxide
Roger Brown Martin Joseph Thomas Leigh and Michael L. Swain
pg 1003; DOI:
10.1039/P19770001003
PDF
Configuration of 2-arylmethylene-2,3-dihydro-5-methylbenzo[b]thiophen-3-ones
Liam S. S. Réamonn and W. Ivo O'Sullivan
pg 1009; DOI:
10.1039/P19770001009
PDF
Total synthesis of thiazolinone analogues of indolmycin
Michael R. Harnden and Nicholas D. Wright
pg 1012; DOI:
10.1039/P19770001012
PDF
Flavonoids from Vernonia fasciculata Michx. Isolation of genkwanin and a new flavone disaccharide, fasciculatin
Nand K. Narain
pg 1018; DOI:
10.1039/P19770001018
PDF
Spirocyclisation reactions of diethyl pyridazine-4,5-dicarboxylate with 1,3-binucleophiles
Giorgio Adembri Stefano Chimichi Rodolfo Nesi and Mirella Scotton
pg 1020; DOI:
10.1039/P19770001020
PDF
Some products from nitrosation of indoles
Anthony H. Jackson David N. Johnston and Patrick V. R. Shannon
pg 1024; DOI:
10.1039/P19770001024
PDF
Electrocyclic reactions. Part 11. 1,5-Diphenylpentadienide
Charles W. Shoppee and George N. Henderson
pg 1028; DOI:
10.1039/P19770001028
PDF
Oxymetallation. Part 10. Synthesis of -mercurioalkyl hydroperoxides and bis--mercurioalkyl peroxides from hydrogen peroxide
A. J. Bloodworth and M. E. Loveitt
pg 1031; DOI:
10.1039/P19770001031
PDF
Tautomerism in N-heterocycles. Part 3. 3,4,5-Trimercaptopyridazine
Gordon B. Barlin and Pasupuleti Lakshminarayana
pg 1038; DOI:
10.1039/P19770001038
PDF
The reactivity of organophosphorus compounds. Part 31. On the formation of 1,4-diphenylnaphthalene from o-bromophenol and 1,2,5-triphenylphosphole, and related reactions
J. I. G. Cadogan Alan G. Rowley Robert J. Scott and Norman H. Wilson
pg 1044; DOI:
10.1039/P19770001044
PDF
Synthesis of fully aromatic cyclic polyethers
David E. Kime and J. Konrad Norymberski
pg 1048; DOI:
10.1039/P19770001048
PDF
Stereochemistry of -halogeno-sulphoxides. Part 5. Absolute stereochemistry of -chlorination of benzyl t-butyl sulphoxide
(Mrs.) Rita Annunziata and Stefano Colonna
pg 1052; DOI:
10.1039/P19770001052
PDF
S-alkylation of sulphides by an activated carbohydrate epimine under acidic catalysis: formation of -acetamido-sulphides. Part 1
Brian Bannister
pg 1057; DOI:
10.1039/P19770001057
PDF
Organometallic reactions. Addition reactions of benzenethiol to unsaturated systems catalysed by trimethyl(phenylthio)-silane or -stannane
Alfredo Ricci Roberto Danieli and Graziella Pirazzini
pg 1069; DOI:
10.1039/P19770001069
PDF
Conservation of the chair-like transition state by base-catalysed epimerization of meso-tetramethyl hexa-1,5-diene-2,3,4,5-tetracarboxylate prior to its Cope rearrangement
Cornelius J. Meyer and David F. Schneider
pg 1073; DOI:
10.1039/P19770001073
PDF
Enolate anions as protecting groups for ketones during reduction by hydride
Derek H. R. Barton Robert H. Hesse Colin Wilshire and Maurice M. Pechet
pg 1075; DOI:
10.1039/P19770001075
PDF
Tritium nuclear magnetic resonance spectroscopy. Part 7. New information from the tritium distribution in biosynthetically labelled penicillic acid
John A. Elvidge Devendra K. Jaiswal John R. Jones and Robert Thomas
pg 1080; DOI:
10.1039/P19770001080
PDF
Naphthalen-1,4-imine derivatives with bridgehead substituents
John M. Vernon Munir Ahmed and John M. Moran
pg 1084; DOI:
10.1039/P19770001084
PDF
Mechanism of reduction of 3,4,5-triphenylfuran-2(5H)-ones by lithium aluminium hydride
Dinesh K. Dikshit Kishan L. Munshi Randhir S. Kapil and Nitya Anand
pg 1087; DOI:
10.1039/P19770001087
PDF
Reactions of carboxylic acids with dichloro- and dibromo-alkanes in the presence of fluoride ions: effects of very strong hydrogen bonding
James H. Clark John Emsley and Otho P. A. Hoyte
pg 1091; DOI:
10.1039/P19770001091
PDF
Purines, pyrimidines, and imidazoles. Part 46. Some acyclic D-arabinose imidazole and purine nucleosides
Grahame Mackenzie Gordon Shaw and David H. Robinson
pg 1094; DOI:
10.1039/P19770001094
PDF
Photochemical transformations. Part 35. A simple synthesis of racemic terrein
Derek H. R. Barton and Lumbertus A. Hulshof
pg 1103; DOI:
10.1039/P19770001103
PDF
Photochemical transformations. Part 36. Synthesis and photolytic ring contraction of mesoionic 2-alkylthiothiazol-4-ones; a new route to -lactams
Derek H. R. Barton Ernst Buschmann Johannes Haüsler Cedric W. Holzapfel Tuvia Sheradsky and Derryck A. Taylor
pg 1107; DOI:
10.1039/P19770001107
PDF
Deamination of primary amines with dinitrogen tetraoxide at low temperatures: formation of nitrates
Derek H. R. Barton and Subhash C. Narang
pg 1114; DOI:
10.1039/P19770001114
PDF

Issue 10


Contents pages

pg P021; DOI:
10.1039/P197700FP021
PDF
Studies on lactams. Part 47. Penicillin and cephalosporin analogues with methylthio-substituents
John L. Fahey Barry C. Lange James M. Van der Veen George R. Young and Ajay K. Bose
pg 1117; DOI:
10.1039/P19770001117
PDF
Asymmetric reduction of ketones by using complexes of lithium tetrahydridoaluminate(III) with 1,4:3,6-dianhydro-D-mannitol and 1,3:4,6-di-O-benzylidene-D-mannitol
Neil Baggett and Peter Stribblehill
pg 1123; DOI:
10.1039/P19770001123
PDF
Studies of fluorinated -diketones and related compounds. Part 6. Synthesis and spectroscopic studies of some new fluorinated -thioxo-ketones and their copper chelates
Krishna C. Joshi Vijai N. Pathak and Khetaram Kumawat
pg 1127; DOI:
10.1039/P19770001127
PDF
Chlorination of arylammonium salts in sulphuric acid
Clarence W. Schimelpfenig
pg 1129; DOI:
10.1039/P19770001129
PDF
Organic synthesis using a migrating functional group: [1,2] and [1,3] phenylthio shifts in synthesis via allyl sulphides
Peter Brownbridge and Stuart Warren
pg 1131; DOI:
10.1039/P19770001131
PDF
Torsional barriers in 6-amino-5-formamidopyrimidin-4(3H)-ones
Felix Bergmann Miriam Rahat and Mordecai Rabinovitz
pg 1141; DOI:
10.1039/P19770001141
PDF
Synthesis, crystal and molecular structure of a 1,11-etheno-steroid: 3-methoxy-1,11-ethenoestra-1,3,5(10),9(11)-tetraen-17-one
Colin G. Pitt Douglas H. Rector David H. White Mansukh C. Wani Andrew T. McPhail and Kay D. Onan
pg 1144; DOI:
10.1039/P19770001144
PDF
Studies on the synthesis of heterocyclic compounds. Part 698. An alternative protoberberine synthesis; total synthesis of ()-xylopinine, ()-schefferine, ()-nandinine, ()-corydaline, and ()-thalictricavine
Tetsuji Kametani Toshiji Sugai Yohko Shoji Toshio Honda Fumio Satoh and Keiichiro Fukumoto
pg 1151; DOI:
10.1039/P19770001151
PDF
The rearrangement of isothiochroman sulphonium ylides via a thermal ylide exchange reaction
Roberto Pellicciari Massimo Curini and Paolo Ceccherelli
pg 1155; DOI:
10.1039/P19770001155
PDF
Iodoacetoxylation of 3-t-butylcyclohexene
Richard C. Cambie Diana M. Gash Peter S. Rutledge and Paul D. Woodgate
pg 1157; DOI:
10.1039/P19770001157
PDF
Heterocycles in organic synthesis. Part 3. Reversible dearomatisation of azoles: formation of triazabenzophenanthrenes
Avijit Banerji Julian C. Cass and Alan R. Katritzky
pg 1162; DOI:
10.1039/P19770001162
PDF
Photochemistry of ethyl 4-substituted 2-cyano-1,2-dihydroquinoline-1-carboxylates (Reissert compounds): syntheses of cycloprop[b]indoles
Masazumi Ikeda Saeko Matsugashita Fujio Tabusa and Yasumitsu Tamura
pg 1166; DOI:
10.1039/P19770001166
PDF
Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents
Rosemary J. Hughes Smollie Ncube Andrew Pelter Keith Smith Ei-ichi Negishi and Takao Yoshida
pg 1172; DOI:
10.1039/P19770001172
PDF
Studies in the cyclopropa-arene series: cyclopropa[b]naphthalenes
Alan R. Browne and Brian Halton
pg 1177; DOI:
10.1039/P19770001177
PDF
Terpenoids. Part 40. Oxidative rearrangement of ent-17-norkauran-16-one with thallium(III) nitrate and synthesis of ent-9(815H)abeo-kaurane
Eiichi Fujita and Masahito Ochiai
pg 1182; DOI:
10.1039/P19770001182
PDF
Three syntheses of lacticolorin
Karsten Krohn and Joachim Thiem
pg 1186; DOI:
10.1039/P19770001186
PDF
Cyclisation of 2-(nitroacetyl)benzoic acids
Roger G. Alexander Derek R. Buckle and John M. Tedder
pg 1191; DOI:
10.1039/P19770001191
PDF
Critical chain length for the formation of the -helix in the solid state. Synthesis and conformation of sequential oligopeptides and a polypeptide containing the sequence L-leucyl-L-alanyl-L-leucylglycine
Ryoichi Katakai
pg 1193; DOI:
10.1039/P19770001193
PDF
Imidoyl-substituted oxosulphonium ylides: preparation and reaction with nitrile oxides
Roy Faragher and Thomas L. Gilchrist
pg 1196; DOI:
10.1039/P19770001196
PDF
Formation of benzimidazoles at high pressure
George Holan John J. Evans and Max Linton
pg 1200; DOI:
10.1039/P19770001200
PDF
Metabolites from the sponge Pachymatisma johnstoni; L-6-bromohypaphorine, a new amino-acid (and its crystal structure)
Warwick D. Raverty Ronald H. Thomson and Trevor J. King
pg 1204; DOI:
10.1039/P19770001204
PDF
Calciferol and its relatives. Part 19. Synthetic applications of cyclic orthoesters: stereospecific synthesis of a bicyclic alcohol related to the vitamins D2
Christopher B. Chapleo Peter Hallett Basil Lythgoe Ian Waterhouse and Paul W. Wright
pg 1211; DOI:
10.1039/P19770001211
PDF
Stereochemical aspects of some Claisen rearrangements with cyclic orthoesters
Richard J. Cave Basil Lythgoe David A. Metcalfe and Ian Waterhouse
pg 1218; DOI:
10.1039/P19770001218
PDF
Approaches to the synthesis of compounds containing fused mesoionic rings
Peter N. Preston and Kenneth Turnbull
pg 1229; DOI:
10.1039/P19770001229
PDF
Thio-sugars. Part 8. Methyl 2,3-anhydro-5-thio--D-ribopyranoside and methyl 3,4-anhydro-5-thio--D-ribopyranoside
Derek M. C. Hull Peter F. Orchard and Leonard N. Owen
pg 1234; DOI:
10.1039/P19770001234
PDF

Issue 11


Contents pages

pg P025; DOI:
10.1039/P197700FP025
PDF
Reactions of carbodi-imides with toluene-p-sulphonyl azide in the presence of copper or pentacarbonyliron
Iwao Yamamoto Hiroshi Tokanou Hiro-aki Uemura and Haruo Gotoh
pg 1241; DOI:
10.1039/P19770001241
PDF
Chemical investigation of ceylonese plants. Part 24. New chromenoflavonoids from the bark of Artocarpus nobilis Thw. (Moraceae)
N. Savitri Kumar Gowsala Pavanasasivam M. Uvais S. Sultanbawa and Rajeswari Mageswaran
pg 1243; DOI:
10.1039/P19770001243
PDF
Ring expansion and photochemical ring contraction reactions of tetrahydropyridazinones
Seyhan N. Ee Marjorie L. C. Carter Daniel F. Ortwine Shang-Shing P. Chou and Joel F. Richman
pg 1252; DOI:
10.1039/P19770001252
PDF
Thermal dealkylation of 2,4-bis(alkylamino)-6-chloro-s-triazines. Effect of alkyl group structure. Part 2
ivorad D. Tadid Gordana A. Boni-Carii and Milan D. Mukatirovi
pg 1257; DOI:
10.1039/P19770001257
PDF
Formation of -mono- and -di-methyl or -phenyl derivatives of tosylhydrazones through an in situ sequence by treatment with lithium dimethyl- or diphenyl-cuprate
Sandro Cacchi Marcello Felici and Goffredo Rosini
pg 1260; DOI:
10.1039/P19770001260
PDF
Cyclisations in anhydrous hydrogen fluoride; derivatives of diethyl phenylmalonate
Vernon Askam and Tariq Umer Qazi
pg 1263; DOI:
10.1039/P19770001263
PDF
Synthetic studies with carbonates. Part 6. Syntheses of 2-hydroxyethyl derivatives by reactions of ethylene carbonate with carboxylic acids or heterocycles in the presence of tetraethylammonium halides or under autocatalytic conditions
Teruo Yoshino Shigeru Inaba Hajime Komura and Yoshiharu Ishido
pg 1266; DOI:
10.1039/P19770001266
PDF
Reactions of -imino-nitriles and -esters with carbon disulphide. A new synthesis and some reactions of 2-cyano-3-imino-dithiocarboxylic acids
Motomu Muraoka Tatsuo Yamamoto Sadaki Yamaguchi Fumio Tonosaki Tatsuo Takeshima and Naoaki Fukada
pg 1273; DOI:
10.1039/P19770001273
PDF
Darzens reactions with quinonoid systems. Part 1. Spiro[oxiran-2,9-phenanthrenes] from phenanthrenequinone, and phenanthro-oxazoles from phenanthrenequinone imine or phenanthrenequinone mono-oxime
William I. Awad Zuhair S. Salih and Zakaria H. Aiube
pg 1280; DOI:
10.1039/P19770001280
PDF
Nonbenzenoid aromatic compounds containing a fused four-membered ring. Formation and properties of benzo[3,4]cyclobuta[1,2]cyclohepten-6-one derivatives
Masaru Sato Seiji Ebine and Josuke Tsunetsugu
pg 1282; DOI:
10.1039/P19770001282
PDF
Synthetic studies on terpenoids. Part 19. Synthesis of 3,10,14-trimethyl-1H,11H-tricyclo[9.3.0.0]tetradec-6-en-5-one, a tricyclic ketone related to the ophiobolins
Tushar Kanti Das Phanindra Chandra Dutta Gopinath Kartha and J. M. Bernassau
pg 1287; DOI:
10.1039/P19770001287
PDF
Direct arylation of nitrobenzenes and of heterocycles via an oxygen analogue of the benzidine rearrangement
Tuvia Sheradsky and Eliahu Nov
pg 1296; DOI:
10.1039/P19770001296
PDF
Synthesis of [A-2--diaminobutyric acid, A-19-glutamic acid] sheep insulin
Nicolaos Ferderigos and Panayotis G. Katsoyannis
pg 1299; DOI:
10.1039/P19770001299
PDF
A convenient synthesis of cyclic ether-lactones from olefinic hydroxy-acids
Michiharu Kato Masanori Kageyama and Akira Yoshikoshi
pg 1305; DOI:
10.1039/P19770001305
PDF
Thermal elimination reactions of nitrones. Part 1. Applications, limitations, and stereochemistry
Derek R. Boyd and David C. Neill
pg 1308; DOI:
10.1039/P19770001308
PDF
o-Quinonoid compounds. Part 13. 1,5-Acyl shifts in substituted indenes; conversion of 1-acyl- into 2-acyl-indenes and orienting mechanistic experiments
David W. Jones and Geoffrey Kneen
pg 1313; DOI:
10.1039/P19770001313
PDF
Amidinoacetamides in the synthesis of pyrazines and pteridines
William F. Keir Alexander H. MacLennan and Hamish C. S. Wood
pg 1321; DOI:
10.1039/P19770001321
PDF
Stereoselective formation and rearrangements of naphthalen-2(1H)-one epoxides
John Carnduff and David G. Leppard
pg 1325; DOI:
10.1039/P19770001325
PDF
Decomposition of a 1-hydroperoxynaphthalen-2(1H)-one by bases
John Carnduff and David G. Leppard
pg 1329; DOI:
10.1039/P19770001329
PDF
Metal catalysis in organic reactions. Part 4. Stereospecificity in the dimerization and cyclotrimerization of chiral alk-1-ynes
Giampaolo Giacomelli Anna Maria Caporusso and Luciano Lardicci
pg 1333; DOI:
10.1039/P19770001333
PDF
Unequivocal synthesis of 6-arylpteridines by intramolecular cycloaddition of azahexatrienes
Fumio Yoneda and Masatsugu Higuchi
pg 1336; DOI:
10.1039/P19770001336
PDF
Reactions of carbonyl compounds with tervalent phosphorus reagents. Part 7. Benzaldehyde with chlorodiphenylphosphine in the presence of acetic acid
J. Allen Miller and Denis Stewart
pg 1340; DOI:
10.1039/P19770001340
PDF
Studies in oligosaccharide chemistry. Part 8. Synthesis of lacto-N-triose I, a core chain trisaccharide of human blood-group substances
Claudine Augé and Alain Veyrières
pg 1343; DOI:
10.1039/P19770001343
PDF
Benzene oxide–oxepin. Oxidation to muconaldehyde
Stephen G. Davies and Gordon H. Whitham
pg 1346; DOI:
10.1039/P19770001346
PDF
N-Iodo-amides: mechanism of intramolecular reactions with aromatic rings of amido-radicals in - and -electronic states
Stephen A. Glover and André Goosen
pg 1348; DOI:
10.1039/P19770001348
PDF
Chiroptical properties of N-acetoacetyl--amino-acids, -amino-alcohols, and -amines
Salim S. Sabri Mustafa M. El-Abadelah and Mohammed F. Za'ater
pg 1356; DOI:
10.1039/P19770001356
PDF
Oxidation of the bisdihydrofuran moieties of aflatoxin B1 and sterigmatocystin; conformation of tetrahydrofurobenzofurans
Charles P. Gorst-Allman Pieter S. Steyn and Philippus L. Wessels
pg 1360; DOI:
10.1039/P19770001360
PDF

Issue 12


Contents pages

pg P027; DOI:
10.1039/P197700FP027
PDF
Condensation of perfluoroalkyl iodides with unsaturated nitrogen compounds
Daniéle Cantacuzène Claude Wakselman and Régine Dorme
pg 1365; DOI:
10.1039/P19770001365
PDF
Pyrrolylpolyenes. Part 2. Stereochemistry of Wallemia A and synthesis of its (E)-isomer and other models
Yasmeen Badar Akash K. Chopra Hanwellage W. Dias Michael B. Hursthouse Abdul R. Khokhar Masayoshi Ito Trevor P. Toube and Basil C. L. Weedon
pg 1372; DOI:
10.1039/P19770001372
PDF
Reactions of conjugated arylazocyclohexenes with Grignard reagents; X-ray crystal structure of 1-hydroperoxy-1-(o-methoxyphenylazo)-2-phenylcyclohexane
Silvano Bozzini Sergio Grattion Amerigo Risaliti Antonia Stener Mario Calligaris and Giorgio Nardin
pg 1377; DOI:
10.1039/P19770001377
PDF
Synthetic studies with carbonates. Part 11. D-Glucopyranose 1-carbonate derivatives; pyrolytic behaviour and use for glucosylation of phenols
Yoshiharu Ishido Shigeru Inaba Akira Matsuno Teruo Yoshino and Hideo Umezawa
pg 1382; DOI:
10.1039/P19770001382
PDF
Pyridine-induced shifts in the 1H nuclear magnetic resonance spectra of 20-hydroxypregnane derivatives
George Cooley David N. Kirk Robert E. Morgan and Maria L. Sá e Melo
pg 1390; DOI:
10.1039/P19770001390
PDF
Dicarbonylrhodium(I) complexes of polypyrrole macrocycles. Part 2. Oxidative addition reactions with aldehydes, formates, -oxo-esters, methyl ketones, and aryl halides
Ajita M. Abeysekera Ronald Grigg Jadwiga Trocha-Grimshaw and Venkatappa Viswanatha
pg 1395; DOI:
10.1039/P19770001395
PDF
Proton magnetic resonance studies of sterols. Assignment of methyl signals of C27, C28, C29 analogues
Thomas A. Wittstruck Jacek K. Sliwowski and Eliahu Caspi
pg 1403; DOI:
10.1039/P19770001403
PDF
Structure of aminoglycoside 66-40 C, a novel unsaturated imine produced by Micromonospora inyoensis
D. Huw Davies Alan K. Mallams James McGlotten James B. Morton and Richard W. Tkach
pg 1407; DOI:
10.1039/P19770001407
PDF
Effects of remote unsaturated bonds on nucleophilic aromatic substitution in polyfluoroaromatic compounds. Profound effect of a remote carbonyl group
Gerald M. Brooke Raymond S. Matthews and Alan C. Young
pg 1411; DOI:
10.1039/P19770001411
PDF
Behaviour of 1,3-diferrocenylalkenes and 1,2-diferrocenylethylene in strong acid. Apparent intramolecular reduction of -ferrocenyl carbocations
William M. Horspool Ronald G. Sutherland Bruce J. Thomson and Ian M. Young
pg 1418; DOI:
10.1039/P19770001418
PDF
Synthesis of a cephalosporin analogue
John E. T. Corrie Joseph R. Hlubucek and Gordon Lowe
pg 1421; DOI:
10.1039/P19770001421
PDF
Studies on steroids. Part 41. Conformational analysis of steroidal side chains by proton magnetic resonance spectroscopy
Masami Nakane and Nobuo Ikekawa
pg 1426; DOI:
10.1039/P19770001426
PDF
Preparation of NN-linked bi(heteroaryls) from dehydroacetic acid and 2,6-dimethyl-4-pyrone
A. Sultan Afridi Alan R. Katritzky and Christopher A. Ramsden
pg 1428; DOI:
10.1039/P19770001428
PDF
Synthesis, spectroscopic properties, and chemistry of 4,6-diphenyl-2-pyridones and 4,6-diphenylpyridine-2-thiones and their relationship to isomeric species
A. Sultan Afridi Alan R. Katritzky and Christopher A. Ramsden
pg 1436; DOI:
10.1039/P19770001436
PDF
Fluorination of norbornadiene and 1,4-dihydro-1,4-methanonaphthalene with substituted (difluoroiodo)benzenes
Ana Gregori and Marko Zupan
pg 1446; DOI:
10.1039/P19770001446
PDF
Reactions of formylchromone derivatives. Part 1. Cycloadditions to 2- and 3-(aryliminomethyl)chromones
Alan O. Fitton Jonathan R. Frost Peter G. Houghton and Hans Suschitzky
pg 1450; DOI:
10.1039/P19770001450
PDF
Organic synthesis with a migrating functional group: scope and limitations of diphenylphosphinoyl migration
Alan H. Davidson Chris Earnshaw J. Ian Grayson and Stuart Warren
pg 1452; DOI:
10.1039/P19770001452
PDF
Ene reactions of allenes. Part 3. Reactions of electron-deficient azo-compounds with acyclic allenes and alkenes
Chan Boo Lee and David R. Taylor
pg 1463; DOI:
10.1039/P19770001463
PDF
Cycloaddition reactions of sulphines with benzonitrile oxide
Bianca F. Bonini Gaetano Maccagnani Germana Mazzanti Lambertus Thijs Hubertus P. M. M. Ambrosius and Binne Zwanenburg
pg 1468; DOI:
10.1039/P19770001468
PDF
Preparation of analogues of the carbohydrate moiety of the polyoxins
Karl Bischofberger Abraham J. Brink Olof G. de Villiers Richard H. Hall and Amor Jordaan
pg 1472; DOI:
10.1039/P19770001472
PDF
Transformations of penicillin. Part 8. Preparation of 2-acetylceph-3-em derivatives from carboxy-protected penicillin S-oxides
Maria J. V. de Oliveira Baptista Anthony G. M. Barrett Derek H. R. Barton Moopil Girijavallabhan Richard C. Jennings John Kelly Vasiliki J. Papadimitriou John V. Turner and Norman A. Usher
pg 1477; DOI:
10.1039/P19770001477
PDF
Photochemistry of halogenocarbon compounds. Part 3. Rearrangements involving azaprismanes
Richard D. Chambers and Roderick Middleton
pg 1500; DOI:
10.1039/P19770001500
PDF

Issue 13


Contents pages

pg P029; DOI:
10.1039/P197700FP029
PDF
Chemical investigation of ceylonese plants. Part 27. Extractives of Calophyllum cuneifolium Thw. and Calophyllum soulattri Burm. f. (Guttiferae)
Sarath P. Gunasekera Gamini S. Jayatilake Sathiadevan S. Selliah and M. Uvais S. Sultanbawa
pg 1505; DOI:
10.1039/P19770001505
PDF
The dithiole series. Part 6. Intermediacy of spirothiopyrans in reactions of 3,5-disubstituted 1,2-dithiolylium salts with cationic heterocycles containing reactive methyl groups
Edwin I. G. Brown Derek Leaver and David M. McKinnon
pg 1511; DOI:
10.1039/P19770001511
PDF
Photochemical equivalent of a benzilic acid rearrangement and related conversions
Jan H. van der Westhuizen Daneel Ferreira and David G. Roux
pg 1517; DOI:
10.1039/P19770001517
PDF
Stable carbocations. Part 12. Generation, observation, and properties of ferrocenyl-stabilised vinyl cations
Trevor S. Abram and William E. Watts
pg 1522; DOI:
10.1039/P19770001522
PDF
Stable carbocations. Part 13. Intra-ionic cyclisation reactions of ferrocenyl- and phenyl-stabilised vinyl cations
Trevor S. Abram and William E. Watts
pg 1527; DOI:
10.1039/P19770001527
PDF
Stable carbocations. Part 14. Ferrocenyl-substituted allenyl
Trevor S. Abram and William E. Watts
pg 1532; DOI:
10.1039/P19770001532
PDF
Stable carbocations. Part 15. Double-shift rearrangements of ferrocenylcarbenium ions
Trevor S. Abram T. Derrick Turbitt and William E. Watts
pg 1536; DOI:
10.1039/P19770001536
PDF
Stable carbocations. Part 16. Properties of 2-substituted exo-5,6-trimethylenenorbornan-2-ylium ions
R. Gordon Kinnley William Lawrie and William E. Watts
pg 1542; DOI:
10.1039/P19770001542
PDF
Benzannulenones. Synthesis of 22,23,24,25-tetradehydrodibenzo[a,g]cycloheneicosen-11-one
Jro Ojima Michiko Enkaku and Miyako Ishiyama
pg 1548; DOI:
10.1039/P19770001548
PDF
Diazenium cations. Part 2. Synthesis and mechanism of the reduction of bicyclic cis-diazenium derivatives in alcoholic media
James P. Snyder Michael L. Heyman and Maryanne Gundestrup
pg 1551; DOI:
10.1039/P19770001551
PDF
Elimination reactions of cis- and trans-8a-hydroxy-2-thiadecalin 2,2-dioxide with thionyl chloride. Evidence for intermediacy of ion pairs
Silvio Fabrissin Silvana Fatutta and Amerigo Risaliti
pg 1561; DOI:
10.1039/P19770001561
PDF
Deoxygenation of sugar derivatives by the Wolff–Kishner reaction
Derek Horton Wolfgang Weckerle Léon Odier and Roderick J. Sorenson
pg 1564; DOI:
10.1039/P19770001564
PDF
Synthesis of sulphoxides by intramolecular and intermolecular addition of sulphenic acids to olefins and dienes
D. Neville Jones Douglas R. Hill Derek A. Lewton and Christine Sheppard
pg 1574; DOI:
10.1039/P19770001574
PDF
12-epi-Scalarin and 12-epi-deoxoscalarin, sesterterpenes from the sponge Spongia nitens
Guido Cimino Salvatore De Stefano Luigi Minale and Enrico Trivellone
pg 1587; DOI:
10.1039/P19770001587
PDF
Oxidation of some 4-substituted N-aminopyridinium salts
David G. Doughty and Edward E. Glover
pg 1593; DOI:
10.1039/P19770001593
PDF

Issue 14


Contents pages

pg P031; DOI:
10.1039/P197700FP031
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Chemical constituents of gentianaceae. Part 22. Structures of new 1,3,5-tri- and 1,3,5,6,7-penta-oxygenated xanthones of Canscora decussata Schult
Shibnath Ghosal Kanika Biswas and Ratan K. Chaudhuri
pg 1597; DOI:
10.1039/P19770001597
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Heterocyclic compounds. Part 15. NN-Di-t-butylthiadiaziridine 1,1-dioxide: synthesis and reactions
Hsien-Hsin Chang and Boris Weinstein
pg 1601; DOI:
10.1039/P19770001601
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Reactions involving fluoride ion. Part 14. Anionic -complexes from polyfluorinated s-triazines
Richard D. Chambers Paul D. Philpot and Peter L. Russell
pg 1605; DOI:
10.1039/P19770001605
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2-C-nitrometnyl and 2-C-aminomethyl derivatives of D-ribose. Preparation of 2-C-nitromethyluridines
Abraham J. Brink Olof G. de Villiers and Amor Jordaan
pg 1608; DOI:
10.1039/P19770001608
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Reactions of dehydrodithizone with dimethyl acetylenedicarboxylate and with benzyne. X-Ray crystal structure of azobenzene N-(4,5-bis-methoxycarbonylthiazol-2-yl)imide, a stable dipole
Gerhard V. Boyd Timothy Norris Peter F. Lindley and Mudhafar M. Mahmoud
pg 1612; DOI:
10.1039/P19770001612
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Mononuclear heterocyclic rearrangements. Part 11. Rearrangements of 1,2,4-oxadiazoles, isoxazoles, and 1,2,5-oxadiazoles involving a sulphur atom
Nicolò Vivona Giuseppe Cusmano and Gabriella Macaluso
pg 1616; DOI:
10.1039/P19770001616
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Reactions of 5,6,8,9,10,11-hexahydro-4H-pyrido[3,2,1-jk]carbazole and of 5,6,9,10,11,12-hexahydro-4H,8H-cyclohepta[4,5]pyrrolo[3,2,1-ij]quinoline with arenesulphonyl azides
Gulam A. Bahadur A. Sydney Bailey and Patricia A. Baldry
pg 1619; DOI:
10.1039/P19770001619
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Reaction of ethyl diazoacetate with cobalt porphyrins. Part 3. Structure and reactions of the 2 :1 adducts
Peter Batten Alan L. Hamilton Alan W. Johnson Mailvaganam Mahendran David Ward and Trevor J. King
pg 1623; DOI:
10.1039/P19770001623
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Plant proanthocyanidins. Part 3. Conformational and configurational studies of natural procyanidins
Anthony C. Fletcher Lawrence J. Porter Edwin Haslam and Raj K. Gupta
pg 1628; DOI:
10.1039/P19770001628
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Plant proanthocyanidins. Part 4. Biosynthesis of procyanidins and observations on the metabolism of cyanidin in plants
David Jacques Clive T. Opie Lawrence J. Porter and Edwin Haslam
pg 1637; DOI:
10.1039/P19770001637
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Bis-porphyrin derivatives. Part 1. Reaction of meso-hydroxymethylporphyrinatometal derivatives with acids
Dennis Arnold Alan W. Johnson and Manfred Winter
pg 1643; DOI:
10.1039/P19770001643
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Oxidation of ethyl trans- and cis-3-bromo-1-methyl-2-oxocyclohexanecarboxylates by dimethyl sulphoxide
Kikumasa Sato Seiichi Inoue Masao Hirayama and Masao hashi
pg 1647; DOI:
10.1039/P19770001647
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Synthesis of a new eighteen-membered ring tetrathia[2.1.2.1]metacyclophane with alternating disulphide and methylene linkages
Francesco Bottino Salvatore Foti and Sebastiano Pappalardo
pg 1652; DOI:
10.1039/P19770001652
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Synthesis of a (2,3-dideoxyglyc-2-enopyranosyl)thymine and a (2,3-dideoxyglycopyranosyl)thymine via a 2,2-anhydro-nucleoside
Tatsumi Yamazaki Kazuo Matsuda Hiroshi Sugiyama Shuichi Seto and Naotaka Yamaoka
pg 1654; DOI:
10.1039/P19770001654
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Synthesis and properties of 4,4-bi(cyclopentene)-3,3,5,5-tetraone
Masaji Kasai Makoto Funamizu Masaji Oda and Yoshio Kitahara
pg 1660; DOI:
10.1039/P19770001660
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Biosynthesis of reticuline
Dewan S. Bhakuni Awadhesh N. Singh Shobha Tewari and Randhir S. Kapil
pg 1662; DOI:
10.1039/P19770001662
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Reactions of -dibromocycloalkanones with bases
Kikumasa Sato Seiichi Inoue Shin-ichi Kuranami and Masao hashi
pg 1666; DOI:
10.1039/P19770001666
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Synthesis of thioesters by reactions of carboxylic acids with tris(ethylthio)borane
Andrew Pelter Terence E. Levitt Keith Smith and Ann Jones
pg 1672; DOI:
10.1039/P19770001672
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Total synthesis of the antileukaemic lignan ()-steganacin
Dan Becker Leslie R. Hughes and Ralph A. Raphael
pg 1674; DOI:
10.1039/P19770001674
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Photoreactions of some benzylic sulphones
Graham E. Robinson and John M. Vernon
pg 1682; DOI:
10.1039/P19770001682
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Intramolecular addition of aryl radicals to the azo-group; synthesis and properties of N-(carbazol-9-yl)phenylaminyl radicals
Luisa Benati Giuseppe Placucci Piero Spagnolo Antonio Tundo and Giuseppe Zanardi
pg 1684; DOI:
10.1039/P19770001684
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Action of nitrous acid on some methylpyrimidines
Derek T. Hurst Stephen G. Jonas Jerry Outram and Rosemary A. Patterson
pg 1688; DOI:
10.1039/P19770001688
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N-oxides and related compounds. Part 58. Some precursors of pyridinium methylide
Jayant B. Bapat Jan Epsztajn Alan R. Katritzky and Bernard Plau
pg 1692; DOI:
10.1039/P19770001692
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A new approach to the synthesis of ellipticines
Anthony H. Jackson Paul R. Jenkins and Patrick V. R. Shannon
pg 1698; DOI:
10.1039/P19770001698
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Issue 15


Contents pages

pg P033; DOI:
10.1039/P197700FP033
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Organic reactions in melts and solids. Part 10. Reactions of carboxylic acids and anhydrides with carbamates
Michael Michman Saul Patai and Yitshak Wiesel
pg 1705; DOI:
10.1039/P19770001705
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Allenes. Part 37. The synthesis of allenic barbiturates and thiobarbiturates
Stephen R. Landor Phyllis D. Landor and Paul F. Whiter
pg 1710; DOI:
10.1039/P19770001710
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Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 6. A simple preparation of chlorohydrin benzoates from 1,2-and 1,3-glycols
Thomas G. Back Derek H. R. Barton and Bail L. Rao
pg 1715; DOI:
10.1039/P19770001715
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Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 7. Conversion of thiocarbonates into deoxy-sugars
Derek H. R. Barton and Raman Subramanian
pg 1718; DOI:
10.1039/P19770001718
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Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 8. Synthesis and properties of O-alkyl selenoesters
Derek H. R. Barton Per-Egil Hansen and Kelvin Picker
pg 1723; DOI:
10.1039/P19770001723
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Synthesis of amino-acids by electroreductive coupling of alkyl halides with Schiff's bases
Tameo Iwasaki and Kaoru Harada
pg 1730; DOI:
10.1039/P19770001730
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Structural investigation of lac resin. Part 12. 10-epi- and 2-epi, 10-epi-Shellolic acids and some allylic rearrangements
G. B. Venkata Subramanian Uma Majumdar Virender S. Chauhan K. Nagappa Ganesh and Vijay K. Mahajan
pg 1734; DOI:
10.1039/P19770001734
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Photoreactivity of quinoline derivatives. Part 2. Photodimers of trans-4-styrylbenzo[h]quinoline
Franco Andreani Renato Andrisano Giuliana Salvadori and Maurilio Tramontini
pg 1737; DOI:
10.1039/P19770001737
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Hydrogen bonding in organic synthesis. Part 6. C-Alkylation of -dicarbonyl compounds using tetra-alkylammonium fluorides
James H. Clark and Jack M. Miller
pg 1743; DOI:
10.1039/P19770001743
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N-halogeno-compounds. Part 3. N-Chlorination of some fluorinated aryl- and heteroaryl-amines and anilides
Ronald E. Banks Michael G. Barlow Timothy J. Noakes and Mohamad M. Saleh
pg 1746; DOI:
10.1039/P19770001746
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Electrochemical oxidation of aromatic ethers. Part 4. Intramolecular coupling of diaryl esters
Malcolm Sainsbury and John Wyatt
pg 1750; DOI:
10.1039/P19770001750
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Synthesis of xanthines by cyclization of the Michael-type adducts from 6-aminouracils and diethyl azodiformate
Fumio Yoneda Masatsugu Higuchi and Shigeru Matsumoto
pg 1754; DOI:
10.1039/P19770001754
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To enzyme analogues by lock and key chemistry with crown compounds. Part 1. Enantiomeric differentiation by configurationally chiral cryptands synthesised from L-tartaric acid and D-mannitol
W. David Curtis Dale A. Laidler J. Fraser Stoddart and Graham H. Jones
pg 1756; DOI:
10.1039/P19770001756
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Synthesis of the physostigmine ring system from cycloprop[b]indoles
Masazumi Ikeda Saeko Matsugashita and Yasumitsu Tamura
pg 1770; DOI:
10.1039/P19770001770
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Anodic oxidation. Part 16. A comparison of chemical and electrochemical routes to alkyl diphenylallyl ethers
F. Mpandasoni Banda and Roger Brettle
pg 1773; DOI:
10.1039/P19770001773
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Thio-sugars. Part 9. Derivatives of 3,6-anhydro-5-thio-D-glucose
Derek M. C. Hull and Leonard N. Owen
pg 1777; DOI:
10.1039/P19770001777
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The purple pigments produced by acetylation of 2-(2-oxoindolin-3-yl)-glyoxylates in the presence of pyridine
James A. Ballantine Mahbub Alam and G. William Fishlock
pg 1781; DOI:
10.1039/P19770001781
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C-nucleoside studies. Part 6. Synthesis of 3-[2,3,5-tri-O-benzyl--(and )-D-ribofuranosyl]prop-2-yn-1-ol and related compounds; a new synthesis of 3(5)-(2,3,5-tri-O-benzyl--D-ribofuranosyl)pyrazole
J. Grant Buchanan Allan D. Dunn Alan R. Edgar Roderick J. Hutchison Michael J. Power and Gavin C. Williams
pg 1786; DOI:
10.1039/P19770001786
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Reactions of nucleophiles with some N-methyl-1,2,4-thiadiazolium salts
Stephen Crook and Peter Sykes
pg 1791; DOI:
10.1039/P19770001791
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Issue 16


Contents pages

pg P035; DOI:
10.1039/P197700FP035
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Ionic additions to unsaturated systems. Part 2. Triethylammonium hydrogendichloride as reagent in the addition of hydrogen chloride to alkynes
Jack Cousseau and Lucien Gouin
pg 1797; DOI:
10.1039/P19770001797
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A new triterpenoid glycoside from the leaves of Tetrapanax papyriferum
Makoto Takai Sakae Amagaya and Yukio Ogihara
pg 1801; DOI:
10.1039/P19770001801
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Phosphorus derivatives of amide oximes. Part 1. Synthesis of N2-[bis(dimethylamino)phosphinoyl]amidines, 4,6-disubstituted 2,5-dihydro-1,3,5,2-triazaphosphorine 2-oxides, and 3-dialkylamino-1-dimethylamino-1H-2,1-benzazaphosphole 2-oxides
Lucien Lopez and Jean Barrans
pg 1806; DOI:
10.1039/P19770001806
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Reactions of S-alkyl NN-disubstituted thioamide salts. Part 2. Orthothioamide derivatives
Stephen A. Okecha and Frank Stansfield
pg 1811; DOI:
10.1039/P19770001811
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Polycyclic systems. Part 17. Proton nuclear magnetic resonance spectra of some 11H-lndeno[2,1-a]phenanthrene derivatives; structure of the C26 hydrocarbon (second diels hydrocarbon) from cholesterol
Dhanonjoy Nasipuri Pranab K. Bhattacharya and Dibyendu N. Roy
pg 1814; DOI:
10.1039/P19770001814
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v-Triazolo[4,5-d]pyrimidines (8-azapurines). Part 19. Stability of N-alkyl-8-azapurines. Degradation by cold, dilute acid and base to N-alkyl-4-amino-1,2,3-triazole-5-carbaldehydes and -triazol-5-yl ketones
Adrien Albert and Clara J. Lin
pg 1819; DOI:
10.1039/P19770001819
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Ring expansion of thiochroman-4-one and isothiochroman-4-one with ethyl diazo(lithio)acetate to tetrahydrobenzothiepin -oxoesters
Roberto Pellicciari and Benedetto Natalini
pg 1822; DOI:
10.1039/P19770001822
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Reactions of ethyl azepine-1-carboxylate with heterodienophiles
William S. Murphy and Krishna P. Raman
pg 1824; DOI:
10.1039/P19770001824
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Cope rearrangements of arylvinylhydroxylamines
Tuvia Sheradsky Eliahu Nov Sofia Segal and Arie Frank
pg 1827; DOI:
10.1039/P19770001827
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Electrochemical difunctionalisation of adamantane and further oxidation of substituted adamantanes
Alan Bewick Gary J. Edwards Stephen R. Jones and John M. Mellor
pg 1831; DOI:
10.1039/P19770001831
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Acylarylnitrosamines. Part 12. Decomposition of N-nitrosoacetanilide and p-nitro-N-nitrosoacetanilide in bromotrichloromethane. An answer to the long-standing problem of the mechanism of anomalous dual halogen abstractions
J. I. G. Cadogan John Cook Robin G. M. Landells and John T. Sharp
pg 1835; DOI:
10.1039/P19770001835
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In situ formation of arenediazonium salts and aryl radicals by aprotic nitrosation of 1,3-diaryltriazenes: dual halogen abstraction from bromotrichloromethane, and radical arylation of aromatic compounds
J. I. G. Cadogan Robin G. M. Landells and John T. Sharp
pg 1841; DOI:
10.1039/P19770001841
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Acylarylnitrosamines. Part 13. Promotion of ionic reactions of o- and p-chloro-, o- and p-acetoxy-, and o-acetylthio-N-nitrosoacetanilides. Formation of hydroxybenzenediazonium salts, the carbene 2-oxocyclohexa-3,5-dienylidene, and 1,2,3-benzothiadiazole
John Brennan J. I. G. Cadogan and John T. Sharp
pg 1844; DOI:
10.1039/P19770001844
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Keten. Part 15. Reactions of diphenylketen with some N-alkyl nitrones
Anthony F. Gettins David P. Stokes Giles A. Taylor and Christopher B. Judge
pg 1849; DOI:
10.1039/P19770001849
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Heterocyclic studies. Part 40. Synthesis and unusual tautomerism of some dihydro-imidazo- and -pyrimido-[1,2-a]pyrimidines
Jim Clark and Michael Curphey
pg 1855; DOI:
10.1039/P19770001855
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Studies of 2-oxo- and 2-thioxo-1,2-dihydropyrimidinium salts
Douglas Lloyd Hamish McNab and Kanwaljit S. Tucker
pg 1862; DOI:
10.1039/P19770001862
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Acid-induced reactions of 1-cyclopropyl-1-ferrocenyl-ethanols and -methanols
William M. Horspool and Bruce J. Thomson
pg 1869; DOI:
10.1039/P19770001869
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Tetranortriterpenoids and related substances. Part 18. Two new tetranortriterpenoids with a modified furan ring from the bark of Soymida febrifuga A. Juss (Meliaceae)
Kozhiparambil K. Purushothaman Sundaram Chandrasekharan Joseph D. Connolly and David S. Rycroft
pg 1873; DOI:
10.1039/P19770001873
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Tetranortriterpenoids and related substances. Part 19. Revised structures of atalantolide and atalantin, limonoids from the root bark of Atalantia monophylla correa (Rutaceae)
Balakrishna Sabata Joseph D. Connolly Cecilia Labbé and David S. Rycroft
pg 1875; DOI:
10.1039/P19770001875
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The pyrethrins and related compounds. Part 21. Carbon-13 nuclear magnetic resonance spectra of synthetic pyrethroids
Norman F. Janes
pg 1878; DOI:
10.1039/P19770001878
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Generation of di-isopropylcarbamoyl-lithium from NN-di-isopropylformamide and t-butyl-lithium. Syntheses of -hydroxy- and -oxo-amides
Andrew S. Fletcher Keith Smith and Kalyanaraman Swaminathan
pg 1881; DOI:
10.1039/P19770001881
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Mechanism of hydrolysis of phosphonium salts and ylides
Andrew Schnell and John C. Tebby
pg 1883; DOI:
10.1039/P19770001883
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Natural acetylenes. Part 52. Polyacetylenic acids and aromatic aldehydes from cultures of the fungus Camarophyllus virgineus(Wulfen ex fr.) Kummer
Iain W. Farrell Viktor Thaller and John L. Turner
pg 1886; DOI:
10.1039/P19770001886
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Issue 17


Contents pages

pg P037; DOI:
10.1039/P197700FP037
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Sodium chromate oxidation of enol benzoates. Allylic oxidation versus a novel rearrangement
Amiram Goldblum and Raphael Mechoulam
pg 1889; DOI:
10.1039/P19770001889
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Reactions of carbonyl compounds with tervalent phosporus reagents. Part 8. Acetyldiphenylphosphine oxide
J. Allen Miller and Denis Stewart
pg 1898; DOI:
10.1039/P19770001898
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Reactions of 1,2-diaminobenzene with 1,3-diketones
Siegfried E. Drewes and Ursula J. Upfold
pg 1901; DOI:
10.1039/P19770001901
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Formation and degradation of urea derivatives in the azide method of peptide synthesis. Part 1. The curtius rearrangement and urea formation
Ken Inouye Kunio Watanabe and Masaru Shin
pg 1905; DOI:
10.1039/P19770001905
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Formation and degradation of urea derivatives in the azide method of peptide synthesis. Part 2. Acidolytic degradation of urea derivatives
Ken Inouye and Kunio Watanabe
pg 1911; DOI:
10.1039/P19770001911
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Steroids. Part 20. Rearrangements of 5,6-epoxy-10-ethenyl- and 10-ethenyl-5-hydroxy-steroids
Brian W. Cubberley Ian G. Guest J. Gareth Ll. Jones and Brian A. Marples
pg 1916; DOI:
10.1039/P19770001916
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Addition reactions of heterocyclic compounds. Part 66. The 13C nuclear magnetic resonance spectra and structures of adducts from 2-alkylquinolines and other heterocycles possessing activated 2-substituents with dialkyl acetylenedicarboxylates
R. Morrin Acheson and Garry Procter
pg 1924; DOI:
10.1039/P19770001924
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Generation and some reactions of phenylsulphonylcarbene
Rudolph A. Abramovitch Vazken Alexanian and Joytirmoy Roy
pg 1928; DOI:
10.1039/P19770001928
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1,3-Dipolar character of six-membered aromatic rings. Part 33. Transformations of cycloadducts derived from 3-oxido-1-triazinylpyridiniums
Nicholas Dennis Alan R. Katritzky Gebran J. Sabounji and Lemi Turker
pg 1930; DOI:
10.1039/P19770001930
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Transformations of penicillins: reactions of secopenicillanic acid derivatives with ethyl N-chloro-N-sodiocarbamate
David H. Bremner Malcolm M. Campbell and Graham Johnson
pg 1940; DOI:
10.1039/P19770001940
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Transformations of penicillins: reactions of penam S-oxides with N-chloro-N-sodiocarbamates
David H. Bremner Malcolm M. Campbell and Graham Johnson
pg 1943; DOI:
10.1039/P19770001943
PDF
Terpenoids. Part 41. Reactions of ent-kaurenes and 13-kaurenes with thallium(III) nitrate in 1,2-dimethoxyethane and a mutual allylic rearrangement of the allylic nitrate products
Eiichi Fujita and Masahito Ochiai
pg 1948; DOI:
10.1039/P19770001948
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Use of NN-isopropylidene dipeptides in peptide synthesis
Paul M. Hardy and David J. Samworth
pg 1954; DOI:
10.1039/P19770001954
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Oxidation of 1-aminopyridinium, 1-aminoquinolinium, and 2-aminoisoquinolinium bromides with lead(IV) acetate
John T. Boyers and Edward E. Glover
pg 1960; DOI:
10.1039/P19770001960
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Synthesis of the diastereoisomers of S-(2-carboxypropyl)-L-cysteine and their S-mono- and SS-di-oxides
John F. Carson
pg 1964; DOI:
10.1039/P19770001964
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Heterocyclic studies. Part 41. Disproportionation of acridinium compounds and mass spectra of some acridines
Jim Clark and Mehdi Bakavoli
pg 1966; DOI:
10.1039/P19770001966
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1,3,2-Oxazaphospholidines from (–)-ephedrine. Intermediates for the stereospecific synthesis of optically active dialkyl alkylphosphonothioates and -selenoates, trialkyl phosphoro-thioates and -selenoates, dialkyl methylphosphonates, and trialkyl phosphates
David B. Cooper C. Richard Hall John M. Harrison and Thomas D. Inch
pg 1969; DOI:
10.1039/P19770001969
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Issue 18


Contents pages

pg P039; DOI:
10.1039/P197700FP039
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Steric and electrostatic effects on the elimination of 2- and 3-sulphonyloxy-groups from methyl 4,6-O–benzylidenehexopyranosides
Tatsumi Yamazaki Kazuo Matsuda Hiroshi Sugiyama Shuichi Seto and Naotaka Yamaoka
pg 1981; DOI:
10.1039/P19770001981
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Diazo coupling reactions of some methylpyrimidines
Derek T. Hurst and Mee Ling Wong
pg 1985; DOI:
10.1039/P19770001985
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Steroids and related studies. Part 41. Schmidt reaction with 3-acetoxypregn-5-ene-7,20-dione
Harkishan Singh Tilak Raj Bhardwaj and Dharam Paul
pg 1987; DOI:
10.1039/P19770001987
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Nitration of 7-substituted 1,3,5-triaza-adamantanes
Afarin Edwards and Graham A. Webb
pg 1989; DOI:
10.1039/P19770001989
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Unsaturated carbohydrates. Part 20. Direct conversion of phenyl 1-thiohexoside esters into phenyl 1-thiohex-1-enopyranosid-3-ulose esters
Robert J. Ferrier and Richard H. Furneaux
pg 1993; DOI:
10.1039/P19770001993
PDF
C-5 bromination of some glucopyranuronic acid derivatives
Robert J. Ferrier and Richard H. Furneaux
pg 1996; DOI:
10.1039/P19770001996
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The chemistry of cellobiose and lactose. Part 7. Selective benzoylation of methyl -lactoside
Ram S. Bhatt Leslie Hough and Anthony C. Richardson
pg 2001; DOI:
10.1039/P19770002001
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Phenyloxazoline derivatives of amino-sugars. Part 3. Preparation of intermediates for the synthesis of sphingoglycolipids
Roy Gigg and Robert Conant
pg 2006; DOI:
10.1039/P19770002006
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Synthesis of 3-O-(-D-glucopyranosyl)-1,2-di-O-stearoyl-L-glycerol, a glucosyl diglyceride
Roy Gigg Anna A. E. Penglis and Robert Conant
pg 2014; DOI:
10.1039/P19770002014
PDF
Reissert compound chemistry. Part 5. Formation of pyrrolo[1,2-a]-quinolines and pyrrolo[2,1-a]isoquinolines
Barrie C. Uff Ronald S. Budhram Malcolm F. Consterdine John K. Hicks Brian P. Slingsby and John A. Pemblington
pg 2018; DOI:
10.1039/P19770002018
PDF
Cumulative double bond systems: thermolysis of benzoyl peroxide in the presence of bisaryliminosulphur derivatives
Giorgio De Luca Gabriele Renzi Romano Cipollini and Adriano Pizzabiocca
pg 2022; DOI:
10.1039/P19770002022
PDF
Thienoquinolines. Part 6. Reaction of 2-chloro-3-(1,2-dibromoethyl)-quinolines with thiourea: a convenient synthesis of thieno[2,3-b]-quinolines
Periappa Shanmugam Nachimuthu Soundararajan and Kuppusamy Kanakarajan
pg 2024; DOI:
10.1039/P19770002024
PDF
Synthesis of analogues of bradykinin with replacement of the arginine residues by 4-guanidinophenyl-L-alanine
Stanley Moore Harry D. Law Derek E. Brundish Donald F. Elliott and Roy Wade
pg 2025; DOI:
10.1039/P19770002025
PDF
Hydrogenation of substituted phthalic anhydrides over palladium
Alan J. McAlees Robert McCrindle and David W. Sneddon
pg 2030; DOI:
10.1039/P19770002030
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Reduction of substituted phthalic anhydrides with sodium borohydride
Alan J. McAlees Robert McCrindle and David W. Sneddon
pg 2037; DOI:
10.1039/P19770002037
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Promotion of the catalytic hydrogenation of phthalimide and substituted phthalimides over palladium
Alan J. McAlees Robert McCrindle and David W. Sneddon
pg 2038; DOI:
10.1039/P19770002038
PDF
Total synthesis of swazinecic acid dilactone. Part 1. Synthesis of 2-hydroxy-2-methyl-3,5-dimethylenehexanedioic acid as an intermediate
C. Gordon Gordon-Gray and Chris G. Whiteley
pg 2040; DOI:
10.1039/P19770002040
PDF
Synthesis of 1H-pyrazolo[3,2-c]-s-triazoles and derived azamethine dyes
Joseph Bailey
pg 2047; DOI:
10.1039/P19770002047
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Oxidation of alkylhydrazines by iodine
Daniel M. Brown Gordon H. Jones Brian E. Looker Colin D. McLean and Sydney Middleton
pg 2052; DOI:
10.1039/P19770002052
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Acid-catalysed methanolysis of methylphenylphosphinic amides: dependence of the stereochemistry on the nucleophilicity of the departing amine and the acidity of the reaction medium
Martin J. P. Harger
pg 2057; DOI:
10.1039/P19770002057
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Hydrogen bonding in organic synthesis. Part 7. Intermolecular self-condensation of some enolisable ketones in the presence of fluoride
James H. Clark and Jack M. Miller
pg 2063; DOI:
10.1039/P19770002063
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A novel approach to the formation of quaternary centres and the introduction of angular substituents by using tricarbonyldieneiron complexes
Anthony J. Pearson
pg 2069; DOI:
10.1039/P19770002069
PDF
Phosphorylated sugars. Part 21. Synthesis of 3-deoxy-D-manno- and 3-deoxy-D-gluco-oct-2-ulosonic acid 5-(dihydrogen phosphates)
Robert S. Sarfati Michelle Mondange and Ladislas Szabó
pg 2074; DOI:
10.1039/P19770002074
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Triazines and related products. Part 20. Oxidation of 1-(arylazo)-piperidines with potassium permanganate
Andreas Gescher Colin P. Turnbull and Malcolm F. G. Stevens
pg 2078; DOI:
10.1039/P19770002078
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The chemistry of vinylphosphine chalcogenides. Part 2. Some nucleophilic and electrophilic additions
S. Roderick Postle and Gordon H. Whitham
pg 2084; DOI:
10.1039/P19770002084
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Issue 19


Contents pages

pg P041; DOI:
10.1039/P197700FP041
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Synthesis of some indan-1-ones
Jaysukhlal R. Merchant Meera S. Kamath and Suneel Y. Dike
pg 2089; DOI:
10.1039/P19770002089
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Cyclisation of nitrile imides with alkenyl substituents: routes to 1,2-benzodiazepines and cyclopropa[c]cinnolines
Luisa Garanti and Gaetano Zecchi
pg 2092; DOI:
10.1039/P19770002092
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Photocyclisation and photoisomerisation of 1,3,4- and 1,4,5-triphenylpyrazole
James Grimshaw and David Mannus
pg 2096; DOI:
10.1039/P19770002096
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The structure of clavicipitic acid, an azepinoindole derivative from Claviceps fusiformis
Graham S. King Eric S. Waight Peter G. Mantle and Christine A. Szczyrbak
pg 2099; DOI:
10.1039/P19770002099
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On the reported transformation of -amyrin into oleanolic acid
Robin B. Boar Laurette Joukhadar Manuel de Luque James F. McGhie Derek H. R. Barton Duilio Arigoni Hans G. Brunner and Rudolf Giger
pg 2104; DOI:
10.1039/P19770002104
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Chemical and photochemical cyclisations of 1-alkylidene-1,2,3,4-tetrahydro-2-nicotinoyl- and -isonicotinoyl--carbolines: a regiospecific synthesis of nauclfine
Malcolm Sainsbury and Nigel L. Uttley
pg 2109; DOI:
10.1039/P19770002109
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Colouring matters of the West African red woods Pterocarpus osun and P. soyauxii. Structures of santarubins A and B
Alberto Arnone Lorenzo Camarda Lucio Merlini Gianluca Nasini and David A. H. Taylor
pg 2116; DOI:
10.1039/P19770002116
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13C nuclear magnetic resonance spectral analysis of santalin and santarubin permethyl ethers
Alberto Arnone Lorenzo Camarda Lucio Merlini and Gianluca Nasini
pg 2118; DOI:
10.1039/P19770002118
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Chiroptical studies. Part 92 The circular dichroism of strained, bridged-ring, and other ketones
David N. Kirk
pg 2122; DOI:
10.1039/P19770002122
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Clemmensen reduction. Part 5. Chiral -hydroxy-ketones
Brian R. Davis Gordon W. Rewcastle Ralph J. Stevenson and Paul D. Woodgate
pg 2148; DOI:
10.1039/P19770002148
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Reaction of -aminocinnamonitrile and its N-mono- and NN-di-substituted derivatives with benzonitrile oxides
Antonino Corsaro Ugo Chiacchio and Giovanni Purrello
pg 2154; DOI:
10.1039/P19770002154
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Extractives from Guttiferae. Part 33. Synthesis of the ozonolysis product from dimethylmangostin, 1-hydroxy-3,6,7-trimethoxy-2,8-bis-(2-oxoethyl)xanthone; some 13C nuclear magnetic resonance spectra of xanthones
M. Sum b. Hj. Idris Alan Jefferson and Feodor Scheinmann
pg 2158; DOI:
10.1039/P19770002158
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An improved synthesis of 13-epi-androstanes and of 13-epi-oestranes
Robin B. Boar Francis K. Jetuah James F. McGhie Michael S. Robinson and Derek H. R. Barton
pg 2163; DOI:
10.1039/P19770002163
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Studies in the cyclopropa-arene series: approaches to cyclopropa[a]-naphthalene
Martin G. Banwell Regine Blattner Alan R. Browne John T. Craig and Brian Halton
pg 2165; DOI:
10.1039/P19770002165
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Fluorination with xenon difluoride. Part 15. Stereochemistry of fluorine addition to acenaphthylene and dihydronaphthalenes
Boris ket and Marko Zupan
pg 2169; DOI:
10.1039/P19770002169
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Biomimetic synthesis of acridone alkaloids
Joyce H. Adams Padma Gupta M. Shafiq Khan and John R. Lewis
pg 2173; DOI:
10.1039/P19770002173
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Preparation of some nitro-triesters, and a synthesis of -bis(methoxycarbonyl)--lactones
Roger Brettle and David P. Cummings
pg 2177; DOI:
10.1039/P19770002177
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Carbon-13 nuclear magnetic resonance assignments of some fungal C20 anthraquinones; their biosynthesis in relation to that of aflatoxin B1
Charles P. Gorst-Allman Klaus G. R. Pachler Pieter S. Steyn Philippus L. Wessels and De Buys Scott
pg 2181; DOI:
10.1039/P19770002181
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Affinity chromatography using agarose–triazine derivatives
Thomas Lang Colin J. Suckling and Hamish C. S. Wood
pg 2189; DOI:
10.1039/P19770002189
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Competitive cyclisations of singlet and triplet nitrenes. Part 5. Mechanism of cyclisation of 2-nitrenobiphenyls and related systems
John M. Lindley Ian M. McRobbie Otto Meth-Cohn and Hans Suschitzky
pg 2194; DOI:
10.1039/P19770002194
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Spirans. Part 10. Acid-catalysed rearrangement of oxygen heterocyclic spirans
Arthur W. S. Dick Francis M. Dean David A. Matkin and Malcolm L. Robinson
pg 2204; DOI:
10.1039/P19770002204
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Issue 20


Contents pages

pg P045; DOI:
10.1039/P197700FP045
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Stereochemistry of organophosphorus cyclic compounds. Part 5. Synthesis and geometry of some 4,5-disubstituted 1,3,2-dioxaphospholan-2-thiones and stereochemistry of nucleophilic displacement reactions at phosphorus
Marian Mikoajczyk and Magorzata Witczak
pg 2213; DOI:
10.1039/P19770002213
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2-Isoxazoline derivatives. Part 11. Reactions of nitrile oxides, diazoalkanes, and dienes with 2-oxa-3-azabicyclo[3.2.0]hepta-3,6-diene derivatives
Giorgio Bianchi Carlo De Micheli Anna Gamba Remo Gandolfi and Bruno Rezzani
pg 2222; DOI:
10.1039/P19770002222
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Oxidative, photoinduced, and thermal sulphur–nitrogen bond fission in benzenesulphenanilides
Takao Ando Masatomo Nojima and Niichiro Tokura
pg 2227; DOI:
10.1039/P19770002227
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Reactions of iodine triacetate, iodine trichloride, and iodine pentaoxide with alkenes
Richard C. Cambie David Chambers Peter S. Rutledge and Paul D. Woodgate
pg 2231; DOI:
10.1039/P19770002231
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Synthesis of C-glycosyl compounds. Part 2. Reactions of aldonic acid lactones with ethyl isocyanoacetate
Richard H. Hall Karl Bischofberger Stephen J. Eitelman and Amor Jordaan
pg 2236; DOI:
10.1039/P19770002236
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Stereoselectivity in addition of N-nitrenes to olefins
Robert S. Atkinson and John R. Malpass
pg 2242; DOI:
10.1039/P19770002242
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Iodo-azide adducts of 3-methyl-2-steroids; structure and solvolysis
Richard C. Cambie Peter S. Rutledge Truis Smith-Palmer and Paul D. Woodgate
pg 2250; DOI:
10.1039/P19770002250
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Cytotoxic compounds. Part 21. Chloro-, methoxy-, and methoxy-carbonyl-derivatives of (bis-2-chloroethylamino)-phenols and -anilines
Anthony J. Abela Medici Leonard N. Owen and Constantine Sflomos
pg 2258; DOI:
10.1039/P19770002258
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Acyl anion equivalents: synthesis of ketones and enones from -phenylthioalkylphosphine oxides
J. Ian Grayson and Stuart Warren
pg 2263; DOI:
10.1039/P19770002263
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Scope and limitations of allyl sulphide synthesis by [1,2] and [1,3] phenylthio migration
Peter Brownbridge and Stuart Warren
pg 2272; DOI:
10.1039/P19770002272
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Synthesis of purines by cyclization of the Michael-type adducts from 6-aminopyrimidines and 4-phenyl-1,2,4-triazoline-3,5-dione
Fumio Yoneda Mitsuko Kawamura Shigeru Matsumoto and Masatsugu Higuchi
pg 2285; DOI:
10.1039/P19770002285
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Regioselective cleavage of aromatic methyl ethers by methanesulphonic acid in the presence of methionine
Nobutaka Fujii Hiroshi Irie and Haruaki Yajima
pg 2288; DOI:
10.1039/P19770002288
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Spirans. Part 11. A new method for generating o-quinone methides, and its applications to the synthesis of spirochromans. A note on the autoxidation of a naphthol derivative
Francis M. Dean and David A. Matkin
pg 2289; DOI:
10.1039/P19770002289
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Addition of primary aliphatic amines to 1,2-benzoquinone. The absence of reaction between a secondary amide and 1,2-benzoquinone
Roger Davies and J. Leslie Frahn
pg 2295; DOI:
10.1039/P19770002295
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C-2 and C-4 reactions of cephalosporanates and their (S)- and (R)-oxides with toluene-p-sulphonyl azide, acrylonitrile, and ethyl chloroformate
David H. Bremner and Malcolm M. Campbell
pg 2298; DOI:
10.1039/P19770002298
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Fungal products. Part 20. Transformations of 2- and 3-hydroxylated kaurenoids by Gibberella fujikuroi
Martin W. Lunnon Jake MacMillan and Bernard O. Phinney
pg 2308; DOI:
10.1039/P19770002308
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Terpenoids. Part 7. Diequatorial opening of 2,3-epoxides of ent-kauranes and ent-gibberellanes
Martin W. Lunnon and Jake MacMillan
pg 2317; DOI:
10.1039/P19770002317
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Synthesis of nitidine (8,9-dimethoxy-5-methyl-2,3-methylenedioxybenzo[c]phenanthridinium); a comparison of electrochemical and photochemical methods
William J. Begley and James Grimshaw
pg 2324; DOI:
10.1039/P19770002324
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Reactions of 1,2- and 1,3-amino-alcohols with imidate salts and with ortho esters

pg 2328; DOI:
10.1039/P19770002328
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Nitrogen heterocycles. Part 7. Some reactions of 2-anilinophthalimidine derivatives
Valerio Scartoni Ivano Morelli Antonio Marsili and Serena Catalano
pg 2332; DOI:
10.1039/P19770002332
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Issue 21


Contents pages

pg P047; DOI:
10.1039/P197700FP047
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v-Triazolines. Part 7. 3-Arylaminothiophens from hexahydrothiopyrano[3,4-d]-v-triazoles
Donato Pocar Luisa Maria Rossi Riccardo Stradi and Pasqualina Trimarco
pg 2337; DOI:
10.1039/P19770002337
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Studies in the cyclopropa-arene series: acid-catalysed and thermal decompositions of 1,1-dichloro-2,5-diphenylcyclopropabenzene
Helmut M. Hügel David P. Kelly Alan R. Browne Brian Halton Paul J. Milsom and Anthony D. Woolhouse
pg 2340; DOI:
10.1039/P19770002340
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Synthetic studies in the piperidine alkaloid field. Part 1. The 2-azabicyclo[2.2.2]octan-5-one approach to prosopine
Andrew J. G. Baxter and Andrew B. Holmes
pg 2343; DOI:
10.1039/P19770002343
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Studies on the syntheses of heterocyclic compounds. Part 724. Total syntheses of the quinazolinone alkaloids glycorine, glomerine, homoglomerine, crysogine, and euxylophoricines A and C
Tetsuji Kametani Chu Van Loc Terumi Higa Masataka Ihara and Keiichiro Fukumoto
pg 2347; DOI:
10.1039/P19770002347
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Regio- and stereo-selectivity in [2 +2] photocycloaddition reactions between cyclopent-2-enone and electron-rich alkenes
Daniel Termont Denis De Keukeleire and Maurits Vandewalle
pg 2349; DOI:
10.1039/P19770002349
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An improved method for the use of acetal-substituted Grignard reagents in organic synthesis
Craig P. Forbes George L. Wenteler and Adriaan Wiechers
pg 2353; DOI:
10.1039/P19770002353
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Studies on organic fluorine compounds. Part 23. Diels–Alder reactions of 1,2,3,4-tetrakis(trifluoromethyl)-5-thiabicyclo[2.1.0]pent-2-ene
Yoshiro Kobayashi Itsumaro Kumadaki Akio Ohsawa Yasuo Sekine and Akira Ando
pg 2355; DOI:
10.1039/P19770002355
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Intramolecular cyclisation of arylalkyl isothiocyanates. Part 3. Synthesis of 4,5-dihydro-3H-2-benzazepines and 7,8-dihydro-6H-thieno[3,2-c]-azepines
Roy V. Davies Brian Iddon Michael W. Pickering Hans Suschitzky Peter T. Gallagher Maurice W. Gittos and Malcom D. Robinson
pg 2357; DOI:
10.1039/P19770002357
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v-Triazolines. Part 8. 1-Aryl-4-alkyl- and -aryl-thiomethyl-5-amino-v-triazolines: synthesis and reactions with bases
Goffredo Bolis Donato Pocar Riccardo Stradi and Pasqualina Trimarco
pg 2365; DOI:
10.1039/P19770002365
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Amino-acids and peptides. Part 19. Conformational studies of the monamycins, a family of cyclohexadepsipeptide antibiotics
Cedric H. Hassall W. Anthony Thomas and Michael C. Moschidis
pg 2369; DOI:
10.1039/P19770002369
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A synthetic approach to the indole alkaloid apparicine. Synthesis of the ring skeleton
David I. C. Scopes Malcolm S. Allen Geoffrey J. Hignett Nigel D. V. Wilson Martin Harris and John A. Joule
pg 2376; DOI:
10.1039/P19770002376
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Synthesis of some 9-benzyl-8-azabicyclo[4.3.0]nonan-7-ones
Roger Brettle and David P. Cummings
pg 2385; DOI:
10.1039/P19770002385
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Chromens and citrans derived from phloroacetophenone and phloroglucinaldehyde by citral condensation: regioselectivity, mechanism, and X-ray crystal structures
Michael J. Begley Leslie Crombie Richard W. King David A. Slack and Donald A. Whiting
pg 2393; DOI:
10.1039/P19770002393
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Rearrangement and orientation in citran synthesis. X-Ray crystal structures of (–)-bruceol and a ()-deoxybruceol derivative
Michael J. Begley Leslie Crombie David A. Slack and Donald A. Whiting
pg 2402; DOI:
10.1039/P19770002402
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Bicyclo[4.2.1]non-1-en-8-one; a novel anti-Bredt enone. Synthesis of non-enolisable -diketones from oxo-acids
William Carruthers and Andrew Orridge
pg 2411; DOI:
10.1039/P19770002411
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Reactions of carbonyl compounds with tervalent phosphorus reagents. Part 9. Benzaldehyde with phosphinites in the presence of acetic acid
J. Allen Miller and Denis Stewart
pg 2416; DOI:
10.1039/P19770002416
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The photochemistry of ketones derived from carbohydrates. Part 5. Photochemical cross-pinacolisation of acetalised pyranos-3-ulose derivatives with methanol; a route to branched-chain sugar derivatives
Peter M. Collins V. Ranjit N. Munasinghe and Nathan N. Oparaeche
pg 2423; DOI:
10.1039/P19770002423
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Issue 22


Contents pages

pg P049; DOI:
10.1039/P197700FP049
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Coupling reactions of 1-alkylpyridinium salts. Part 1. With phosphite and phosphinite ions
John G. Carey and John R. Case
pg 2429; DOI:
10.1039/P19770002429
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Coupling reactions of 1-alkylpyridinium salts. Part 2. Reaction of 1-methylpyridinium-4-carboxylate with cyanide and diphenylphosphinite ions
John G. Carey and John R. Case
pg 2431; DOI:
10.1039/P19770002431
PDF
Synthesis of 4,4a-5,6,7,8-hexahydro-5-hydroxy-4a,8-dimethylnaphthalen-2(3H)-one, a versatile intermediate for sesquiterpene synthesis
Michiharu Kato Hiroshi Kurihara Hiroshi Kosugi Masataka Watanabe Shigeru Asuka and Akira Yoshikoshi
pg 2433; DOI:
10.1039/P19770002433
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Condensed thiophen ring systems. Part 20. Synthesis of 5-arylthieno-[3,2-b]pyrroles and 5-arylthieno[3,2-c]pyrazoles
Veronica M. Colburn Brian Iddon and Hans Suschitzky
pg 2436; DOI:
10.1039/P19770002436
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The chemistry of prasinons A and B. Identification of the nitrogen-containing moiety
John Frederick Grove Michi Fukuoka Alan W. Johnson and José N. C. Lopes
pg 2441; DOI:
10.1039/P19770002441
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Naturally occurring compounds related to phenalenone. Part 8. Structure and synthesis of demethylherqueichrysin
David A. Frost David D. Halton and George A. Morrison
pg 2443; DOI:
10.1039/P19770002443
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Electrochemical reactions. Part 19. Intermolecular radical substitution during the reduction of 2-halogeno-N-methylbenzanilides
James Grimshaw Reginald J. Haslett and Jadwiga Trocha-Grimshaw
pg 2448; DOI:
10.1039/P19770002448
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Electrochemical reactions. Part 20. Intramolecular cyclisation during the reduction of 2-chloro-NN-diphenylbenzamides
James Grimshaw and David Mannus
pg 2456; DOI:
10.1039/P19770002456
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Addition of dimethyl acetylenedicarboxylate to 4-(pyrrolidin-1-yl)coumarin and to 1-methyl-4-(pyrrolidin-1-yl)quinolin-2(1H)-one
David J. Haywood and Stewart T. Reid
pg 2457; DOI:
10.1039/P19770002457
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Photochemical transformations. Part 10. Photocycloaddition reactions of 4-hydroxycoumarin with cycloalkenes
David J. Haywood Russell G. Hunt Christopher J. Potter and Stewart T. Reid
pg 2458; DOI:
10.1039/P19770002458
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Photochemical transformations. Part 11. Photorearrangement of 1-(2-pyridyl)- and 1-(3-pyridyl)-2-nitropropenes
Russell G. Hunt and Stewart T. Reid
pg 2462; DOI:
10.1039/P19770002462
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Configurational and conformational studies on the group A peptide antibiotics of the mikamycin (streptogramin, virginiamycin) family
Barrie W. Bycroft
pg 2464; DOI:
10.1039/P19770002464
PDF
Oxidation of steroidal 5-enes with thallium triacetate; a westphalentype rearrangement of epicholesterol
Anchel Schwartz and Erwin Glotter
pg 2470; DOI:
10.1039/P19770002470
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Synthesis of 1,4-oxathian-2-one, 5-methyl-1,4-oxathian-2-one, and 1,4-oxathiepan-2-one
David I. Davies Lyn Hughes Yashwant D. Vankar and Jack E. Baldwin
pg 2476; DOI:
10.1039/P19770002476
PDF
Syntheses based on 1,2-secopenicillins. Part 5. Penicillin analogues with electron-withdrawing 2-substituents
Edward G. Brain A. John Eglington John H. C. Nayler Neal F. Osborne Robert Southgate and Patricia Tolliday
pg 2479; DOI:
10.1039/P19770002479
PDF
Photoinduced transformations. Part 36. Stereochemical integrity of the terminus of the migrating carbon in the photo-Beckmann rearrangements of some cholestanone oximes
Hiroshi Suginome and Fujio Yagihashi
pg 2488; DOI:
10.1039/P19770002488
PDF
The reaction of -dodecatrienediylnickel with allene and reactions of the resulting bis--allylnickel intermediates with carbon monoxide and alkyl isocyanides
Raymond Baker and Alison H. Copeland
pg 2497; DOI:
10.1039/P19770002497
PDF
Tetracycline studies. Part 5. New syntheses of anthracenes and anthraquinones through benzophenone carbanions
Michael J. Broadhurst Cedric H. Hassall and Gareth J. Thomas
pg 2502; DOI:
10.1039/P19770002502
PDF
Preparation of benzyl ethers of 1,2-dideoxy-2-methyl--D-glucopyranoso-[2,1-d]-2-oxazoline for use in oligosaccharide synthesis
Patrick Rollin and Pierre Sinaÿ
pg 2513; DOI:
10.1039/P19770002513
PDF
Cytotoxic compounds. Part 22. Reactions of 2,2-iminodiethanol with some chloronitrobenzenes
Anthony J. Abela Medici Leonard N. Owen and Constantine Sflomos
pg 2517; DOI:
10.1039/P19770002517
PDF

Issue 23


Contents pages

pg P051; DOI:
10.1039/P197700FP051
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Cycloaddition of nitrosobenzene to N-ethoxycarbonylazepine
William S. Murphy Krishna P. Raman and Brian J. Hathaway
pg 2521; DOI:
10.1039/P19770002521
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A synthetic approach to cyclo-octa-2,5,7-triene-1,4-dione
Penelope A. Chaloner Andrew B. Holmes M. Anthony McKervey and Ralph A. Raphael
pg 2524; DOI:
10.1039/P19770002524
PDF
Pterins. Part 2. Stereochemistry of catalytic reduction of 6-methyl- and 6,7-dimethyl-pterin and of 2,4-diamino-6-methylpteridine
Wilfred L. F. Armarego and Henning Schou
pg 2529; DOI:
10.1039/P19770002529
PDF
Heterocyclic syntheses with malonyl chloride. Part 12. Confirmatory and revisionary evidence for structures of products derived from 2-alkyl-(or -aryl-)thio-7-chloropyrano[3,4-e][1,3]oxazine-4,5-diones
Jasim M. A. Al-Rawi and John A. Elvidge
pg 2536; DOI:
10.1039/P19770002536
PDF
Biosynthesis of porphyrins and related macrocycles. Part 11. Studies on biosynthesis of the phytyl chain of chlorophyll a by use of carbon-13
Edward H. Ahrens jun. D. Clive Williams and Alan R. Battersby
pg 2540; DOI:
10.1039/P19770002540
PDF
Reinvestigation of the synthesis of 3-dimethylallyl-4-hydroxy-2-quinolones. A novel route to tetracyclic heteroaromatic compounds
Richard Oels Richard Storer and Douglas W. Young
pg 2546; DOI:
10.1039/P19770002546
PDF
Some chemistry of 13-iso-steroids
Robert C. Sheppard and Stephen Turner
pg 2551; DOI:
10.1039/P19770002551
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Autoxidation of 3,4-dihydro-1-methylnaphthalen-2(1H)-one
Dhanonjoy Nasipuri Gautam Das and (Miss) Ila De Dalal
pg 2558; DOI:
10.1039/P19770002558
PDF
Insertion of carbon monoxide and n-butyl isocyanide into bis--allylnickel intermediates derived from reaction of -octadienediylnickel and allene
Raymond Baker and Alison H. Copeland
pg 2560; DOI:
10.1039/P19770002560
PDF
Steroids derived from fusidic acid. Part 2. Synthesis of an 8, 14-dimethyl-18-norandrostane. A revised mechanism
William S. Murphy and David Cocker
pg 2565; DOI:
10.1039/P19770002565
PDF
The photoaddition of aliphatic amines to benzene
Michael Bellas D. Bryce-Smith the late Michael T. Clarke Andrew Gilbert Garune Klunkin Stefan Krestonosich Carl Manning and Steve Wilson
pg 2571; DOI:
10.1039/P19770002571
PDF
Synthetic studies on the construction of the fundamental skeleton of erythroxydiol X. Syntheses of 3a,10a-dimethyl-(3a,4a,6a,10a,10b)-perhydrocyclopropa[j]phenanthrene-5,8-dione and 8-benzoyloxy-3a,10a-dimethyl-(3a,4a,6a,10a,10b)-perhydrocyclopropa[j]phenanthren-3-one
Tatsuhiko Nakano and A. K. Banerjee
pg 2581; DOI:
10.1039/P19770002581
PDF
Oxidation of deoxyhumulones with air. Evidence of divergent and sequential products from deoxyhumulones
Patrick V. R. Shannon and Gareth D. John
pg 2585; DOI:
10.1039/P19770002585
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The reactivity of polyhydric phenols towards air and m-chloroperbenzoic acid. The nature of the monomeric products
Gareth D. John and Patrick V. R. Shannon
pg 2593; DOI:
10.1039/P19770002593
PDF
Microbiological transformations of 3-acetoxy-17a-aza-D-homo-5-androstan-17-one and of 3-acetoxy-5-androstan-17-one with the fungus Cunninghamella elegans
Trevor A. Crabb John A. Saul and Roger O. Williams
pg 2599; DOI:
10.1039/P19770002599
PDF
Fluorination of benzofuran and of N-acylindoles with trifluorofluorooxymethane
Derek H. R. Barton Robert H. Hesse Graham P. Jackman and M. M. Pechet
pg 2604; DOI:
10.1039/P19770002604
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Calciferol and its relatives. Part 20. A synthesis of Windaus and Grundmann's C19 ketone
Basil Lythgoe David A. Roberts and Ian Waterhouse
pg 2608; DOI:
10.1039/P19770002608
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